抄録
Subphthalocyanine (SubPc) and its benzo ring-removed analogue, subporphyrazine (SubPz), bearing 1,3-dithiole-2-one (S2CO) groups as a new class of substituents were synthesized. In addition to the perturbed optical properties due to the presence of electron-withdrawing S2CO units, the deep bowl-shaped structure of the SubPz derivative allowed concave-convex interaction to form a unique co-crystal structure with C60. Finally, using the reactivity of the peripheral S2CO units, S2CO-fused SubPc was successfully converted into tetrathiafulvalene (TTF)-annulated SubPc in a yield higher than that of the direct synthesis from a TTF-fused phthalonitrile.
| 元の言語 | 英語 |
|---|---|
| ジャーナル | Organic Letters |
| DOI | |
| 出版物ステータス | 印刷前のE-pub - 4 12 2019 |
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1,3-Dithiole-2-one-Fused Subphthalocyanine and Subporphyrazine : Synthesis and Properties Arising from the 1,3-Dithiole-2-one Units. / Wang, Yemei; Uchihara, Koya; Mori, Shigeki; Furuta, Hiroyuki; Shimizu, Soji.
：: Organic Letters, 12.04.2019.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - 1,3-Dithiole-2-one-Fused Subphthalocyanine and Subporphyrazine
T2 - Synthesis and Properties Arising from the 1,3-Dithiole-2-one Units
AU - Wang, Yemei
AU - Uchihara, Koya
AU - Mori, Shigeki
AU - Furuta, Hiroyuki
AU - Shimizu, Soji
PY - 2019/4/12
Y1 - 2019/4/12
N2 - Subphthalocyanine (SubPc) and its benzo ring-removed analogue, subporphyrazine (SubPz), bearing 1,3-dithiole-2-one (S2CO) groups as a new class of substituents were synthesized. In addition to the perturbed optical properties due to the presence of electron-withdrawing S2CO units, the deep bowl-shaped structure of the SubPz derivative allowed concave-convex interaction to form a unique co-crystal structure with C60. Finally, using the reactivity of the peripheral S2CO units, S2CO-fused SubPc was successfully converted into tetrathiafulvalene (TTF)-annulated SubPc in a yield higher than that of the direct synthesis from a TTF-fused phthalonitrile.
AB - Subphthalocyanine (SubPc) and its benzo ring-removed analogue, subporphyrazine (SubPz), bearing 1,3-dithiole-2-one (S2CO) groups as a new class of substituents were synthesized. In addition to the perturbed optical properties due to the presence of electron-withdrawing S2CO units, the deep bowl-shaped structure of the SubPz derivative allowed concave-convex interaction to form a unique co-crystal structure with C60. Finally, using the reactivity of the peripheral S2CO units, S2CO-fused SubPc was successfully converted into tetrathiafulvalene (TTF)-annulated SubPc in a yield higher than that of the direct synthesis from a TTF-fused phthalonitrile.
U2 - 10.1021/acs.orglett.9b00752
DO - 10.1021/acs.orglett.9b00752
M3 - Article
C2 - 30977374
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
ER -