2-(Phosphinoaryl)pyridine ligand (2): Asymmetric allylic alkylation of 2-cycloalkenyl carboxylate

K. Ito; R. Kashiwagi; S. Hayashi; T. Uchida; T. Katsuki

doi:10.1055/s-2001-10794

2-(Phosphinoaryl)pyridine ligand (2): Asymmetric allylic alkylation of 2-cycloalkenyl carboxylate

K. Ito, R. Kashiwagi, S. Hayashi, T. Uchida, T. Katsuki

研究成果: Contribution to journal › Article › 査読

19 被引用数 (Scopus)

抄録

Palladium complex of 2-(phosphinoaryl)pyridine 1b, which is an effective catalyst for asymmetric allylic alkylation (denoted as AAA) of acyclic alkenyl carboxylate, was also found to be a highly effective catalyst for AAA of cyclic alkenyl carboxylate: high enantioselectivities of 87% ee and 94% ee were achieved in the reactions of 2-cyclohexenyl and 2-cycloheptenyl pivalates, respectively.

本文言語	英語
ページ（範囲）	284-286
ページ数	3
ジャーナル	Synlett
号	2
DOI	https://doi.org/10.1055/s-2001-10794
出版ステータス	出版済み - 2001
外部発表	はい

All Science Journal Classification (ASJC) codes

有機化学

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10.1055/s-2001-10794

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title = "2-(Phosphinoaryl)pyridine ligand (2): Asymmetric allylic alkylation of 2-cycloalkenyl carboxylate",

abstract = "Palladium complex of 2-(phosphinoaryl)pyridine 1b, which is an effective catalyst for asymmetric allylic alkylation (denoted as AAA) of acyclic alkenyl carboxylate, was also found to be a highly effective catalyst for AAA of cyclic alkenyl carboxylate: high enantioselectivities of 87% ee and 94% ee were achieved in the reactions of 2-cyclohexenyl and 2-cycloheptenyl pivalates, respectively.",

author = "K. Ito and R. Kashiwagi and S. Hayashi and T. Uchida and T. Katsuki",

year = "2001",

doi = "10.1055/s-2001-10794",

language = "English",

pages = "284--286",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

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T1 - 2-(Phosphinoaryl)pyridine ligand (2)

T2 - Asymmetric allylic alkylation of 2-cycloalkenyl carboxylate

AU - Ito, K.

AU - Kashiwagi, R.

AU - Hayashi, S.

AU - Uchida, T.

AU - Katsuki, T.

PY - 2001

Y1 - 2001

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AB - Palladium complex of 2-(phosphinoaryl)pyridine 1b, which is an effective catalyst for asymmetric allylic alkylation (denoted as AAA) of acyclic alkenyl carboxylate, was also found to be a highly effective catalyst for AAA of cyclic alkenyl carboxylate: high enantioselectivities of 87% ee and 94% ee were achieved in the reactions of 2-cyclohexenyl and 2-cycloheptenyl pivalates, respectively.

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JO - Synlett

JF - Synlett

SN - 0936-5214

IS - 2

ER -

2-(Phosphinoaryl)pyridine ligand (2): Asymmetric allylic alkylation of 2-cycloalkenyl carboxylate

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