2,1,3-benzothiadiazole dimers: Preparation, structure, and transannular electronic interactions of syn-and anti-[2.2](4,7)benzothiadiazolophanes

Motonori Watanabe, Kenta Goto, Mamoru Fujitsuka, Sachiko Tojo, Tetsuro Majima, Teruo Shinmyozu

研究成果: Contribution to journalArticle査読

29 被引用数 (Scopus)

抄録

The cyclophanes comprised of two 2,1,3-benzothiadiazole (BTD) rings, anti-and syn-[2.2](4,7)benzothiadiazolophanes (anti-1 and syn-1), were prepared for the first time. The differences of the physical properties in the overlapping mode of the π-systems are clearly observed, and syn-1 shows much more significant transannular π-electronic interactions than anti-1 especially in the redox properties and the stability of the radical anion species.

本文言語英語
ページ(範囲)1155-1161
ページ数7
ジャーナルBulletin of the Chemical Society of Japan
83
10
DOI
出版ステータス出版済み - 2010

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

フィンガープリント 「2,1,3-benzothiadiazole dimers: Preparation, structure, and transannular electronic interactions of syn-and anti-[2.2](4,7)benzothiadiazolophanes」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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