(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Ken Sakai; Manabu Osada; Yoshimi Yokoyama; Yasushi Tomita; Taro Tsubomura

doi:10.1107/S1600536803013801

(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Ken Sakai, Manabu Osada, Yoshimi Yokoyama, Yasushi Tomita, Taro Tsubomura

無機・分析化学

研究成果: ジャーナルへの寄稿 › 記事

7 引用（Scopus）

抜粋

In the title compound, [Pt(C₁₀H₈N₂)(C ₁₁H₁₁N₂)₂](ClO₄) ₄, the square-planar PtN₄ coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

元の言語	英語
ページ（範囲）	m512-m514
ジャーナル	Acta Crystallographica Section E: Structure Reports Online
巻	59
発行部数	7
DOI	https://doi.org/10.1107/S1600536803013801
出版物ステータス	出版済み - 7 1 2003

フィンガープリント

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

これを引用

Sakai, K., Osada, M., Yokoyama, Y., Tomita, Y., & Tsubomura, T. (2003). (2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate. Acta Crystallographica Section E: Structure Reports Online, 59(7), m512-m514. https://doi.org/10.1107/S1600536803013801

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title = "(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate",

abstract = "In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) {\AA} out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) {\AA}.",

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T1 - (2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

AU - Sakai, Ken

AU - Osada, Manabu

AU - Yokoyama, Yoshimi

AU - Tomita, Yasushi

AU - Tsubomura, Taro

PY - 2003/7/1

Y1 - 2003/7/1

N2 - In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

AB - In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

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文献にアクセス

10.1107/S1600536803013801