(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Ken Sakai, Manabu Osada, Yoshimi Yokoyama, Yasushi Tomita, Taro Tsubomura

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

本文言語英語
ページ(範囲)m512-m514
ジャーナルActa Crystallographica Section E: Structure Reports Online
59
7
DOI
出版ステータス出版済み - 7 1 2003
外部発表はい

All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学

フィンガープリント

「(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル