(2,2′-Bipyridine)bis(N-methyl-4,4′-bi-pyridinium)platinum(II) tetraperchlorate

Ken Sakai, Manabu Osada, Yoshimi Yokoyama, Yasushi Tomita, Taro Tsubomura

研究成果: ジャーナルへの寄稿記事

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In the title compound, [Pt(C10H8N2)(C 11H11N2)2](ClO4) 4, the square-planar PtN4 coordination geometry is slightly deformed, with the coordinated N atom of one of the N-methyl-4,4′-bipyridinium (MQ) ligands 0.262 (8) Å out of the plane defined by the rest of the coordinated N atoms and the Pt atom. The exceptional behavior of this MQ ligand is interpreted in terms of the electrostatic interactions between the positively charged MQ ligands and the perchlorate anions, where the N(MQ)⋯O(perchlorate) distances are in the range 2.932 (12)-3.259 (13) Å.

元の言語英語
ページ(範囲)m512-m514
ジャーナルActa Crystallographica Section E: Structure Reports Online
59
発行部数7
DOI
出版物ステータス出版済み - 7 1 2003

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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