2,6-Bis(porphyrin)-substituted pyrazine: a new class of supramolecular synthon binding to a transition-metal ion and fullerene (C60)

Yusaku Eda, Kennosuke Itoh, Yoshio Ito, Toshio Kawato

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

2,6-Disubstituted-3,5-dimethylpyrazines have been synthesized via biased acetal synthesis from symmetric 2,3,5,6-tetrakis(chloromethyl)pyrazine. The pyrazine ligands coordinated to trans-dichloropalladium(II) at the nitrogen whose neighboring carbons were connected to less hindered methyl groups. 2,6-Bis(porphyrin)-substituted pyrazine bound C60 to yield 1:1 inclusion complex. The binding of C60 with the pyrazine ligand and its zinc complex was determined by ESI-MS, NMR, and fluorescence spectroscopic analyses.

本文言語英語
ページ(範囲)282-288
ページ数7
ジャーナルTetrahedron
65
1
DOI
出版ステータス出版済み - 1 3 2009

All Science Journal Classification (ASJC) codes

  • 生化学
  • 創薬
  • 有機化学

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