抄録
Here we report the synthesis and characterization of a series of new phenylene-vinylene tectons. The study by scanning tunneling microscopy of their supramolecular self-assembly at the interface between a phenyloctane solution and highly oriented pyrolytic graphite demonstrates that variation of concentration and length of alkyl chains led to the formation of different networks, a compact one and a nanoporous one, with a fine control of the lattice parameters. The study of guest-host properties of the nanoporous network revealed a selectivity toward guest compounds according to their shape and size. Moreover, the statistical analysis of pore-to-pore guest dynamics evidences an anisotropic diffusion process.
本文言語 | 英語 |
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論文番号 | 025602 |
ジャーナル | Nanotechnology |
巻 | 28 |
号 | 2 |
DOI | |
出版ステータス | 出版済み - 1月 13 2017 |
!!!All Science Journal Classification (ASJC) codes
- バイオエンジニアリング
- 化学 (全般)
- 材料科学(全般)
- 材料力学
- 機械工学
- 電子工学および電気工学