抄録
(Chemical Equation Presented) The cycloaddition of o-(silylmethyl)benzylic carbonates with imines proceeded in the presence of the Pd(η3- C3H5)Cp-DPPPent catalyst, affording the tetrahydroisoquinolines in good to high yields. The reaction rate was remarkably increased by a fluoride additive. In the catalytic cycloaddition, the palladium(0) reacted with the benzylic substrate to form 2-palladaindane, which works as an o-xylylene equivalent. The catalytic reaction is equivalent to the hetero-Diels-Alder reaction of o-xylylene with imines.
本文言語 | 英語 |
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ページ(範囲) | 12904-12905 |
ページ数 | 2 |
ジャーナル | Journal of the American Chemical Society |
巻 | 131 |
号 | 36 |
DOI | |
出版ステータス | 出版済み - 9月 16 2009 |
All Science Journal Classification (ASJC) codes
- 触媒
- 化学 (全般)
- 生化学
- コロイド化学および表面化学