4,5-bis(diarylmethylene)-1,3-dithiole: A novel helical electron donor exhibiting electrochromic behavior

Takanori Suzuki; Shintaro Mikum; Yusuke Ishigaki; Hiroki Higuchi; Hidetoshi Kawai; Kenshu Fujiwara

doi:10.1246/cl.2009.748

4,5-bis(diarylmethylene)-1,3-dithiole: A novel helical electron donor exhibiting electrochromic behavior

Takanori Suzuki, Shintaro Mikum, Yusuke Ishigaki, Hiroki Higuchi, Hidetoshi Kawai, Kenshu Fujiwara

融合材料部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

5 被引用数 (Scopus)

抄録

Vivid color change from intense yellow to deep purple was observed upon electrochemcal oxidation of the title donor 1 to bis(Michler's hydrol blue)-type dication 1 ²⁺. Since the interconversion was also accompanied by drastic geometric changes, configurational stability of the helical π-arrangement is modified upon redox reactions.

本文言語	英語
ページ（範囲）	748-749
ページ数	2
ジャーナル	Chemistry Letters
巻	38
号	7
DOI	https://doi.org/10.1246/cl.2009.748
出版ステータス	出版済み - 2009

!!!All Science Journal Classification (ASJC) codes

化学 (全般)

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10.1246/cl.2009.748

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title = "4,5-bis(diarylmethylene)-1,3-dithiole: A novel helical electron donor exhibiting electrochromic behavior",

abstract = "Vivid color change from intense yellow to deep purple was observed upon electrochemcal oxidation of the title donor 1 to bis(Michler's hydrol blue)-type dication 1 2+. Since the interconversion was also accompanied by drastic geometric changes, configurational stability of the helical π-arrangement is modified upon redox reactions.",

author = "Takanori Suzuki and Shintaro Mikum and Yusuke Ishigaki and Hiroki Higuchi and Hidetoshi Kawai and Kenshu Fujiwara",

year = "2009",

doi = "10.1246/cl.2009.748",

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T2 - A novel helical electron donor exhibiting electrochromic behavior

AU - Suzuki, Takanori

AU - Mikum, Shintaro

AU - Ishigaki, Yusuke

AU - Higuchi, Hiroki

AU - Kawai, Hidetoshi

AU - Fujiwara, Kenshu

PY - 2009

Y1 - 2009

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AB - Vivid color change from intense yellow to deep purple was observed upon electrochemcal oxidation of the title donor 1 to bis(Michler's hydrol blue)-type dication 1 2+. Since the interconversion was also accompanied by drastic geometric changes, configurational stability of the helical π-arrangement is modified upon redox reactions.

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4,5-bis(diarylmethylene)-1,3-dithiole: A novel helical electron donor exhibiting electrochromic behavior

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!!!All Science Journal Classification (ASJC) codes

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