5-Hydroxymethylfurfural Synthesis from Monosaccharides by a Biphasic Reaction-Extraction System Using a Microreactor and Extractor

Yosuke Muranaka, Kenta Matsubara, Taisuke Maki, Shusaku Asano, Hiroyuki Nakagawa, Kazuhiro Mae

研究成果: ジャーナルへの寄稿学術誌査読

19 被引用数 (Scopus)

抄録

5-Hydroxymethylfurfural (HMF) was synthesized from monosaccharides by a biphasic reaction system using a microreactor. The biphasic reaction system realized an immediate extraction and stabilization of product HMF, which further degrades under the reaction conditions. Segmented flow was utilized for an efficient reaction-extraction tool. The effect of extraction ability was evaluated based on the extraction phase/reaction phase partition coefficient of HMF. A Lewis acid catalyst was introduced to overcome the obstacle of the reaction, which was clarified as the isomerization of glucose to fructose, and improved the HMF yield to 85 mol % under the condition of T = 180 °C and τ = 47 min. The recovery of the product HMF was also examined using a constructed microextraction system, and HMF was selectively recovered from the extraction phase.

本文言語英語
ページ(範囲)9384-9390
ページ数7
ジャーナルACS Omega
5
16
DOI
出版ステータス出版済み - 4月 28 2020

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)

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