[6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane

Joseph K.H. Hui, Mark J. MacLachlan

研究成果: Contribution to journalArticle査読

79 被引用数 (Scopus)

抄録

Hexagon-shaped [6 + 6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N2O2 coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(ii), analogous to the conformations observed for cyclohexane.

本文言語英語
ページ(範囲)2480-2482
ページ数3
ジャーナルChemical Communications
23
DOI
出版ステータス出版済み - 1 1 2006
外部発表はい

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

フィンガープリント 「[6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル