[6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane

Joseph K.H. Hui, Mark J. MacLachlan

研究成果: ジャーナルへの寄稿記事

75 引用 (Scopus)

抄録

Hexagon-shaped [6 + 6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N2O2 coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(ii), analogous to the conformations observed for cyclohexane.

元の言語英語
ページ(範囲)2480-2482
ページ数3
ジャーナルChemical Communications
発行部数23
DOI
出版物ステータス出版済み - 6 19 2006

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Imines
Schiff Bases
Cyclohexane
Conformations
Boats
Mass spectrometry
Geometry

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

これを引用

[6 + 6] Schiff-base macrocycles with 12 imines : Giant analogues of cyclohexane. / Hui, Joseph K.H.; MacLachlan, Mark J.

:: Chemical Communications, 番号 23, 19.06.2006, p. 2480-2482.

研究成果: ジャーナルへの寄稿記事

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