[6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane

Joseph K.H. Hui; Mark J. MacLachlan

doi:10.1039/b603985e

[6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane

Joseph K.H. Hui, Mark J. MacLachlan

研究成果: ジャーナルへの寄稿 › 記事

79 引用（Scopus）

抜粋

Hexagon-shaped [6 + 6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N₂O₂ coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(ii), analogous to the conformations observed for cyclohexane.

元の言語	英語
ページ（範囲）	2480-2482
ページ数	3
ジャーナル	Chemical Communications
発行部数	23
DOI	https://doi.org/10.1039/b603985e
出版物ステータス	出版済み - 1 1 2006
外部発表	Yes

フィンガープリント

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

これを引用

Hui, J. K. H., & MacLachlan, M. J. (2006). [6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane. Chemical Communications, (23), 2480-2482. https://doi.org/10.1039/b603985e

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abstract = "Hexagon-shaped [6 + 6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N2O2 coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(ii), analogous to the conformations observed for cyclohexane.",

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文献にアクセス

10.1039/b603985e