[6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane

Joseph K.H. Hui, Mark J. MacLachlan

研究成果: ジャーナルへの寄稿 › 記事

75 引用 (Scopus)

抄録

Hexagon-shaped [6 + 6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N2O2 coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(ii), analogous to the conformations observed for cyclohexane.

元の言語英語
ページ（範囲）2480-2482
ページ数3
ジャーナルChemical Communications
発行部数23
DOI
出版物ステータス出版済み - 6 19 2006

Fingerprint

Imines
Schiff Bases
Cyclohexane
Conformations
Boats
Mass spectrometry
Geometry

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

これを引用

[6 + 6] Schiff-base macrocycles with 12 imines : Giant analogues of cyclohexane. / Hui, Joseph K.H.; MacLachlan, Mark J.

：: Chemical Communications, 番号 23, 19.06.2006, p. 2480-2482.

研究成果: ジャーナルへの寄稿 › 記事

Hui, JKH & MacLachlan, MJ 2006, '[6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane', Chemical Communications, 番号 23, pp. 2480-2482. https://doi.org/10.1039/b603985e
Hui JKH, MacLachlan MJ. [6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane. Chemical Communications. 2006 6 19;(23):2480-2482. https://doi.org/10.1039/b603985e
Hui, Joseph K.H. ; MacLachlan, Mark J. / [6 + 6] Schiff-base macrocycles with 12 imines : Giant analogues of cyclohexane. ：: Chemical Communications. 2006 ; 番号 23. pp. 2480-2482.
@article{1cb18c1e66884f15b43960235bb47013,
title = "[6 + 6] Schiff-base macrocycles with 12 imines: Giant analogues of cyclohexane",
abstract = "Hexagon-shaped [6 + 6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N2O2 coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(ii), analogous to the conformations observed for cyclohexane.",
author = "Hui, {Joseph K.H.} and MacLachlan, {Mark J.}",
year = "2006",
month = "6",
day = "19",
doi = "10.1039/b603985e",
language = "English",
pages = "2480--2482",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "23",

}

TY - JOUR

T1 - [6 + 6] Schiff-base macrocycles with 12 imines

T2 - Giant analogues of cyclohexane

AU - Hui, Joseph K.H.

AU - MacLachlan, Mark J.

PY - 2006/6/19

Y1 - 2006/6/19

N2 - Hexagon-shaped [6 + 6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N2O2 coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(ii), analogous to the conformations observed for cyclohexane.

AB - Hexagon-shaped [6 + 6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N2O2 coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(ii), analogous to the conformations observed for cyclohexane.

UR - http://www.scopus.com/inward/record.url?scp=33745054938&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33745054938&partnerID=8YFLogxK

U2 - 10.1039/b603985e

DO - 10.1039/b603985e

M3 - Article

C2 - 16758022

AN - SCOPUS:33745054938

SP - 2480

EP - 2482

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 23

ER -

文献にアクセス