[60]fullerene can reinforce the organogel structure of porphyrin-appended cholesterol derivatives: Novel odd-even effect of the (CH2)n spacer on the organogel stability

Tsutomu Ishi- i, Ritsuko Iguchi, Erwin Snip, Masato Ikeda, Seiji Shinkai

研究成果: ジャーナルへの寄稿学術誌査読

129 被引用数 (Scopus)

抄録

The influence of added [60]fullerene on the gelation ability of Zn(II) porphyrin appended cholestrol derivatives was discussed. A highly ordered aggregation mode was induced by the intermolecular Zn(II) porphyrin-[60]fullerene interaction that forced porphyrin moieties to form regular sandwich complexes with [60]fullerene. The analysis showed that the slight structural charge in gelators was multiplicatively reflected by the higher order structure of the organogel fibers.

本文言語英語
ページ(範囲)5825-5833
ページ数9
ジャーナルLangmuir
17
19
DOI
出版ステータス出版済み - 9月 18 2001

All Science Journal Classification (ASJC) codes

  • 材料科学(全般)
  • 凝縮系物理学
  • 表面および界面
  • 分光学
  • 電気化学

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