9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

Tatsuya Aotake; Mitsuharu Suzuki; Naoki Aratani; Junpei Yuasa; Daiki Kuzuhara; Hironobu Hayashi; Haruyuki Nakano; Tsuyoshi Kawai; Jishan Wu; Hiroko Yamada

doi:10.1039/c4cc10104a

9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

Tatsuya Aotake, Mitsuharu Suzuki, Naoki Aratani, Junpei Yuasa, Daiki Kuzuhara, Hironobu Hayashi, Haruyuki Nakano, Tsuyoshi Kawai, Jishan Wu, Hiroko Yamada

複合領域化学

研究成果: Contribution to journal › Article › 査読

12 被引用数 (Scopus)

抄録

Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is

本文言語	英語
ページ（範囲）	6734-6737
ページ数	4
ジャーナル	Chemical Communications
巻	51
号	31
DOI	https://doi.org/10.1039/c4cc10104a
出版ステータス	出版済み - 4 21 2015

All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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9,9′-Anthryl-anthroxyl radicals : Strategic stabilization of highly reactive phenoxyl radicals. / Aotake, Tatsuya; Suzuki, Mitsuharu; Aratani, Naoki; Yuasa, Junpei; Kuzuhara, Daiki; Hayashi, Hironobu; Nakano, Haruyuki; Kawai, Tsuyoshi; Wu, Jishan; Yamada, Hiroko.

In: Chemical Communications, Vol. 51, No. 31, 21.04.2015, p. 6734-6737.

研究成果: Contribution to journal › Article › 査読

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AU - Aotake, Tatsuya

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AU - Aratani, Naoki

AU - Yuasa, Junpei

AU - Kuzuhara, Daiki

AU - Hayashi, Hironobu

AU - Nakano, Haruyuki

AU - Kawai, Tsuyoshi

AU - Wu, Jishan

AU - Yamada, Hiroko

PY - 2015/4/21

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9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

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All Science Journal Classification (ASJC) codes

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