9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

Tatsuya Aotake; Mitsuharu Suzuki; Naoki Aratani; Junpei Yuasa; Daiki Kuzuhara; Hironobu Hayashi; Haruyuki Nakano; Tsuyoshi Kawai; Jishan Wu; Hiroko Yamada

doi:10.1039/c4cc10104a

9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

Tatsuya Aotake, Mitsuharu Suzuki, Naoki Aratani, Junpei Yuasa, Daiki Kuzuhara, Hironobu Hayashi, Haruyuki Nakano, Tsuyoshi Kawai, Jishan Wu, Hiroko Yamada

複合領域化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

14 被引用数 (Scopus)

抄録

Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is

本文言語	英語
ページ（範囲）	6734-6737
ページ数	4
ジャーナル	Chemical Communications
巻	51
号	31
DOI	https://doi.org/10.1039/c4cc10104a
出版ステータス	出版済み - 4月 21 2015

!!!All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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title = "9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals",

abstract = "Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is",

author = "Tatsuya Aotake and Mitsuharu Suzuki and Naoki Aratani and Junpei Yuasa and Daiki Kuzuhara and Hironobu Hayashi and Haruyuki Nakano and Tsuyoshi Kawai and Jishan Wu and Hiroko Yamada",

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year = "2015",

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day = "21",

doi = "10.1039/c4cc10104a",

language = "English",

volume = "51",

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journal = "Chemical Communications",

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T1 - 9,9′-Anthryl-anthroxyl radicals

T2 - Strategic stabilization of highly reactive phenoxyl radicals

AU - Aotake, Tatsuya

AU - Suzuki, Mitsuharu

AU - Aratani, Naoki

AU - Yuasa, Junpei

AU - Kuzuhara, Daiki

AU - Hayashi, Hironobu

AU - Nakano, Haruyuki

AU - Kawai, Tsuyoshi

AU - Wu, Jishan

AU - Yamada, Hiroko

PY - 2015/4/21

Y1 - 2015/4/21

N2 - Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is

AB - Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days. This journal is

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JF - Chemical Communications

SN - 1359-7345

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ER -

9,9′-Anthryl-anthroxyl radicals: Strategic stabilization of highly reactive phenoxyl radicals

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!!!All Science Journal Classification (ASJC) codes

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