A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides

Hiroyuki Morimoto, Tetsu Tsubogo, Nichole D. Litvinas, John F. Hartwig

研究成果: Contribution to journalArticle査読

371 被引用数 (Scopus)

抄録

(Chemical Presented) Well compatible: The trifluoromethylations and perfluoroalkylations of aryl iodides and some aryl bromides with trifluoromethyl and perfluoroalkylcopper(I) phenanthroline complexes occur with broad scope at 25-50 8C (see scheme). The trifluoromethyl complex is prepared from inexpensive reagents and can be used in situ or isolated. The reactions tolerate a range of substituents and also occur with heteroaromatic systems.

本文言語英語
ページ(範囲)3793-3798
ページ数6
ジャーナルAngewandte Chemie - International Edition
50
16
DOI
出版ステータス出版済み - 4 11 2011
外部発表はい

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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