TY - JOUR
T1 - A compressed octahedral cobalt(II) complex in the crystal structure of diaqua[6,6′-sulfanediylbis(2,2′-bipyridine)]cobalt(II) dinitrate Li Guo-Ling
AU - Li, Guo Ling
AU - Sato, Osamu
N1 - Publisher Copyright:
© Li and Sato 2017.
PY - 2017
Y1 - 2017
N2 - The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C20H14N4S)(H2O)2]2+ cation and two NO3 - anions. In the complex, [Co(C20H14N4S)(H2O)2]2+ cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the CoII cation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2 coordination sphere. The NO3 - anions are linked to the [Co(C20H14N4S)(H2O)2]2+ cations via O-H·O hydrogen bonds, yielding a layered arrangement parallel to (001).
AB - The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C20H14N4S)(H2O)2]2+ cation and two NO3 - anions. In the complex, [Co(C20H14N4S)(H2O)2]2+ cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the CoII cation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2 coordination sphere. The NO3 - anions are linked to the [Co(C20H14N4S)(H2O)2]2+ cations via O-H·O hydrogen bonds, yielding a layered arrangement parallel to (001).
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U2 - 10.1107/S2056989017008428
DO - 10.1107/S2056989017008428
M3 - Article
AN - SCOPUS:85023176874
VL - 73
SP - 993
EP - 995
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 2056-9890
ER -