A compressed octahedral cobalt(II) complex in the crystal structure of diaqua[6,6′-sulfanediylbis(2,2′-bipyridine)]cobalt(II) dinitrate Li Guo-Ling

Guo Ling Li; Osamu Sato

doi:10.1107/S2056989017008428

A compressed octahedral cobalt(II) complex in the crystal structure of diaqua[6,6′-sulfanediylbis(2,2′-bipyridine)]cobalt(II) dinitrate Li Guo-Ling

Guo Ling Li, Osamu Sato

物質基盤化学部門

研究成果: Contribution to journal › Article › 査読

3 被引用数 (Scopus)

抄録

The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C₂₀H₁₄N₄S)(H₂O)₂]²⁺ cation and two NO₃ ^- anions. In the complex, [Co(C₂₀H₁₄N₄S)(H₂O)₂]²⁺ cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the Co^II cation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2 coordination sphere. The NO3 ^- anions are linked to the [Co(C₂₀H₁₄N₄S)(H₂O)₂]²⁺ cations via O-H·O hydrogen bonds, yielding a layered arrangement parallel to (001).

本文言語	英語
ページ（範囲）	993-995
ページ数	3
ジャーナル	Acta Crystallographica Section E: Crystallographic Communications
巻	73
DOI	https://doi.org/10.1107/S2056989017008428
出版ステータス	出版済み - 2017

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

文献へのアクセス

10.1107/S2056989017008428

フィンガープリント「A compressed octahedral cobalt(II) complex in the crystal structure of diaqua[6,6′-sulfanediylbis(2,2′-bipyridine)]cobalt(II) dinitrate Li Guo-Ling」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{60351edd486748fe83c43761a16be68b,

title = "A compressed octahedral cobalt(II) complex in the crystal structure of diaqua[6,6′-sulfanediylbis(2,2′-bipyridine)]cobalt(II) dinitrate Li Guo-Ling",

abstract = "The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C20H14N4S)(H2O)2]2+ cation and two NO3 - anions. In the complex, [Co(C20H14N4S)(H2O)2]2+ cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the CoII cation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2 coordination sphere. The NO3 - anions are linked to the [Co(C20H14N4S)(H2O)2]2+ cations via O-H·O hydrogen bonds, yielding a layered arrangement parallel to (001).",

author = "Li, {Guo Ling} and Osamu Sato",

year = "2017",

doi = "10.1107/S2056989017008428",

language = "English",

volume = "73",

pages = "993--995",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - A compressed octahedral cobalt(II) complex in the crystal structure of diaqua[6,6′-sulfanediylbis(2,2′-bipyridine)]cobalt(II) dinitrate Li Guo-Ling

AU - Li, Guo Ling

AU - Sato, Osamu

PY - 2017

Y1 - 2017

N2 - The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C20H14N4S)(H2O)2]2+ cation and two NO3 - anions. In the complex, [Co(C20H14N4S)(H2O)2]2+ cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the CoII cation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2 coordination sphere. The NO3 - anions are linked to the [Co(C20H14N4S)(H2O)2]2+ cations via O-H·O hydrogen bonds, yielding a layered arrangement parallel to (001).

AB - The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C20H14N4S)(H2O)2]2+ cation and two NO3 - anions. In the complex, [Co(C20H14N4S)(H2O)2]2+ cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the CoII cation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2 coordination sphere. The NO3 - anions are linked to the [Co(C20H14N4S)(H2O)2]2+ cations via O-H·O hydrogen bonds, yielding a layered arrangement parallel to (001).

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JO - Acta Crystallographica Section E: Crystallographic Communications

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