A compressed octahedral cobalt(II) complex in the crystal structure of diaqua[6,6′-sulfanediylbis(2,2′-bipyridine)]cobalt(II) dinitrate Li Guo-Ling

Guo Ling Li, Osamu Sato

研究成果: Contribution to journalArticle査読

3 被引用数 (Scopus)

抄録

The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C20H14N4S)(H2O)2]2+ cation and two NO3 - anions. In the complex, [Co(C20H14N4S)(H2O)2]2+ cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the CoII cation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2 coordination sphere. The NO3 - anions are linked to the [Co(C20H14N4S)(H2O)2]2+ cations via O-H·O hydrogen bonds, yielding a layered arrangement parallel to (001).

本文言語英語
ページ(範囲)993-995
ページ数3
ジャーナルActa Crystallographica Section E: Crystallographic Communications
73
DOI
出版ステータス出版済み - 2017

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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