A convenient method for the synthesis of protic 2-(tertiary phosphino)-1-amines and Their Cp*RuCl complexes

Masato Ito, Akihide Osaku, Chika Kobayashi, Akira Shiibashi, Takao Ikariya

研究成果: Contribution to journalArticle査読

36 被引用数 (Scopus)

抄録

A variety of protic 2-(tertiary phosphino)-1-amines (R2PCH 2CHR'NHR", P̃NH) have been prepared from 2-oxazolidinones and secondary phosphines using a newly developed acid-promoted decarboxylatie C-P bond formation reaction. Treatment of the resulting chiral P̃NH compounds with Cp*RuCl(isoprene) in CH2CI2 smoothly furnished chiral Cp*RuCl(P-NH) complexes with a typical three-legged piano-stool structure, which prove to be excellent catalyst precursors for asymmetric reactions, including the isomerization of allylic alcohols and hydrogenation of imides.

本文言語英語
ページ(範囲)390-393
ページ数4
ジャーナルOrganometallics
28
2
DOI
出版ステータス出版済み - 1 26 2009
外部発表はい

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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