A cuboidal Cu4S4 cluster supported by bulky iminothiolate ligands: synthesis, solid-state structure, and solution study

Yoshiki Ozawa, Hiroki Iida, Hidetoshi Kiyooka, Kazutaka Nobori, Keishiro Tahara, Toshikazu Ono, Masaaki Abe

研究成果: Contribution to journalArticle査読

抄録

A new tetracopper(I) complex containing a cuboidal Cu4S4 core, [Cu4(dap)4], where dap1 is dibenzodiazepinethiolate(1), has been synthesized and structurally characterized by single-crystal X-ray diffraction analysis. The monoanionic iminothiolate ligand dap1 renders the cluster framework exceptionally stable to retain the tetranuclear structure in solution, which allows us to examine for the first time the solution properties of this class of clusters, including UV-vis and NMR spectroscopy and cyclic voltammetry.

本文言語英語
ページ(範囲)616-622
ページ数7
ジャーナルBulletin of the Chemical Society of Japan
94
2
DOI
出版ステータス出版済み - 2021

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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