A cyano-bridged CrIIICoII ferromagnet with a chiral nanotubular structure constituted of interlocked single and double helices

Yuan Zhu Zhang; Osamu Sato

doi:10.1021/ic900224b

A cyano-bridged Cr^IIICo^II ferromagnet with a chiral nanotubular structure constituted of interlocked single and double helices

Yuan Zhu Zhang, Osamu Sato

物質基盤化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

53 被引用数 (Scopus)

抄録

We have synthesized an unprecedented 3D cyano-bridged Cr^IIICo ^II compound that self-assembles into a periodically ordered, homochiral interlocking structure composed of left-handed single helices and right-handed double-helical strands. It displays fourconnected 6 ⁴8² chiral networks and exhibits ferromagnetic order below 12 K. The formation of the helical structure results in the creation of helical tubular channels in the crystal.

本文言語	英語
ページ（範囲）	1271-1273
ページ数	3
ジャーナル	Inorganic Chemistry
巻	49
号	4
DOI	https://doi.org/10.1021/ic900224b
出版ステータス	出版済み - 2月 15 2010

!!!All Science Journal Classification (ASJC) codes

物理化学および理論化学
無機化学

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10.1021/ic900224b

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引用スタイル

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title = "A cyano-bridged CrIIICoII ferromagnet with a chiral nanotubular structure constituted of interlocked single and double helices",

abstract = "We have synthesized an unprecedented 3D cyano-bridged CrIIICo II compound that self-assembles into a periodically ordered, homochiral interlocking structure composed of left-handed single helices and right-handed double-helical strands. It displays fourconnected 6 482 chiral networks and exhibits ferromagnetic order below 12 K. The formation of the helical structure results in the creation of helical tubular channels in the crystal.",

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Y1 - 2010/2/15

N2 - We have synthesized an unprecedented 3D cyano-bridged CrIIICo II compound that self-assembles into a periodically ordered, homochiral interlocking structure composed of left-handed single helices and right-handed double-helical strands. It displays fourconnected 6 482 chiral networks and exhibits ferromagnetic order below 12 K. The formation of the helical structure results in the creation of helical tubular channels in the crystal.

AB - We have synthesized an unprecedented 3D cyano-bridged CrIIICo II compound that self-assembles into a periodically ordered, homochiral interlocking structure composed of left-handed single helices and right-handed double-helical strands. It displays fourconnected 6 482 chiral networks and exhibits ferromagnetic order below 12 K. The formation of the helical structure results in the creation of helical tubular channels in the crystal.

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