A dendritic porphyrin receptor for C60 which features a profound positive allosteric effect

Masatsugu Ayabe, Atsushi Ikeda, Yohei Kubo, Masayuki Takeuchi, Seiji Shinkai

研究成果: ジャーナルへの寄稿学術誌査読

98 被引用数 (Scopus)

抄録

Treble clefts: The dendritic porphyrin receptor 1 has three fullerene-binding clefts, each of which consists of two face-to-face-oriented porphyrins. [60]Fullerene guests bind to each subunit, successively suppressing the rotational freedom ("domino" effect) and the guest-binding proceeds according to positive homotropic allosterism. As expected, the binding constant achieved in this system is large.

本文言語英語
ページ(範囲)2790-2792
ページ数3
ジャーナルAngewandte Chemie - International Edition
41
15
DOI
出版ステータス出版済み - 8月 2 2002

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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