A dinuclear Ni(μ-H)Ru complex derived from H2

Seiji Ogo, Ryota Kabe, Keiji Uehara, Bunsho Kure, Takashi Nishimura, Saija C. Menon, Ryosuke Harada, Shunichi Fukuzumi, Yoshiki Higuchi, Takashi Ohhara, Taro Tamada, Ryota Kuroki

研究成果: ジャーナルへの寄稿記事

195 引用 (Scopus)

抜粋

Models of the active site in [NiFe]hydrogenase enzymes have proven challenging to prepare. We isolated a paramagnetic dinuclear nickel-ruthenium complex with a bridging hydrido ligand from the heterolytic cleavage of H 2 by a dinuclear NiRu aqua complex in water under ambient conditions (20°C and 1 atmosphere pressure). The structure of the hexacoordinate Ni(μ-H)Ru complex was unequivocally determined by neutron diffraction analysis, and it comes closest to an effective analog for the core structure of the proposed active form of the enzyme.

元の言語英語
ページ(範囲)585-587
ページ数3
ジャーナルScience
316
発行部数5824
DOI
出版物ステータス出版済み - 4 27 2007

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • General

これを引用

Ogo, S., Kabe, R., Uehara, K., Kure, B., Nishimura, T., Menon, S. C., ... Kuroki, R. (2007). A dinuclear Ni(μ-H)Ru complex derived from H2. Science, 316(5824), 585-587. https://doi.org/10.1126/science.1138751