A low-spin ruthenium(IV)-oxo complex: Does the spin state have an impact on the reactivity?

Takahiko Kojima, Yuichirou Hirai, Tomoya Ishizuka, Yoshihito Shiota, Kazunari Yoshizawa, Kenichiro Ikemura, Takashi Ogura, Shunichi Fukuzumi

研究成果: Contribution to journalArticle

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Spin doesn't matter: A ruthenium(II)-aqua complex bearing a pentadentate pyridylamine with a carboxylate group as a ligand affords a seven-coordinate low-spin (S=0) ruthenium(IV)-oxo complex (see structure) by oxidation through proton-coupled electron transfer. Comparison of the reactivity of the low-spin and an intermediate-spin (S=1) RuIV-oxo complexes revealed that the spin state does not affect the reactivity of catalytic oxidation of organic compounds.

元の言語英語
ページ(範囲)8449-8453
ページ数5
ジャーナルAngewandte Chemie - International Edition
49
発行部数45
DOI
出版物ステータス出版済み - 11 2 2010

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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