A low-spin ruthenium(IV)-oxo complex

Does the spin state have an impact on the reactivity?

Takahiko Kojima, Yuichirou Hirai, Tomoya Ishizuka, Yoshihito Shiota, Kazunari Yoshizawa, Kenichiro Ikemura, Takashi Ogura, Shunichi Fukuzumi

研究成果: ジャーナルへの寄稿記事

50 引用 (Scopus)

抄録

Spin doesn't matter: A ruthenium(II)-aqua complex bearing a pentadentate pyridylamine with a carboxylate group as a ligand affords a seven-coordinate low-spin (S=0) ruthenium(IV)-oxo complex (see structure) by oxidation through proton-coupled electron transfer. Comparison of the reactivity of the low-spin and an intermediate-spin (S=1) RuIV-oxo complexes revealed that the spin state does not affect the reactivity of catalytic oxidation of organic compounds.

元の言語英語
ページ(範囲)8449-8453
ページ数5
ジャーナルAngewandte Chemie - International Edition
49
発行部数45
DOI
出版物ステータス出版済み - 11 2 2010

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Ruthenium
Bearings (structural)
Catalytic oxidation
Organic compounds
Protons
Ligands
Oxidation
Electrons

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

これを引用

A low-spin ruthenium(IV)-oxo complex : Does the spin state have an impact on the reactivity? / Kojima, Takahiko; Hirai, Yuichirou; Ishizuka, Tomoya; Shiota, Yoshihito; Yoshizawa, Kazunari; Ikemura, Kenichiro; Ogura, Takashi; Fukuzumi, Shunichi.

:: Angewandte Chemie - International Edition, 巻 49, 番号 45, 02.11.2010, p. 8449-8453.

研究成果: ジャーナルへの寄稿記事

Kojima, Takahiko ; Hirai, Yuichirou ; Ishizuka, Tomoya ; Shiota, Yoshihito ; Yoshizawa, Kazunari ; Ikemura, Kenichiro ; Ogura, Takashi ; Fukuzumi, Shunichi. / A low-spin ruthenium(IV)-oxo complex : Does the spin state have an impact on the reactivity?. :: Angewandte Chemie - International Edition. 2010 ; 巻 49, 番号 45. pp. 8449-8453.
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