TY - JOUR
T1 - A low-spin ruthenium(IV)-oxo complex
T2 - Does the spin state have an impact on the reactivity?
AU - Kojima, Takahiko
AU - Hirai, Yuichirou
AU - Ishizuka, Tomoya
AU - Shiota, Yoshihito
AU - Yoshizawa, Kazunari
AU - Ikemura, Kenichiro
AU - Ogura, Takashi
AU - Fukuzumi, Shunichi
PY - 2010/11/2
Y1 - 2010/11/2
N2 - Spin doesn't matter: A ruthenium(II)-aqua complex bearing a pentadentate pyridylamine with a carboxylate group as a ligand affords a seven-coordinate low-spin (S=0) ruthenium(IV)-oxo complex (see structure) by oxidation through proton-coupled electron transfer. Comparison of the reactivity of the low-spin and an intermediate-spin (S=1) RuIV-oxo complexes revealed that the spin state does not affect the reactivity of catalytic oxidation of organic compounds.
AB - Spin doesn't matter: A ruthenium(II)-aqua complex bearing a pentadentate pyridylamine with a carboxylate group as a ligand affords a seven-coordinate low-spin (S=0) ruthenium(IV)-oxo complex (see structure) by oxidation through proton-coupled electron transfer. Comparison of the reactivity of the low-spin and an intermediate-spin (S=1) RuIV-oxo complexes revealed that the spin state does not affect the reactivity of catalytic oxidation of organic compounds.
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U2 - 10.1002/anie.201002733
DO - 10.1002/anie.201002733
M3 - Article
C2 - 20865710
AN - SCOPUS:78149428977
SN - 1433-7851
VL - 49
SP - 8449
EP - 8453
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 45
ER -