A mer-Triaqua Rh complex with a terpyridine ligand

Daisuke Inoki, Takahiro Matsumoto, Hidetaka Nakai, Seiji Ogo

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

We report the synthesis of a mer-triaqua Rh III complex using terpyridine as a meridional tridentate ligand. This is the first example of a structurally characterized six-coordinated mertriaqua complex for any second- or third-row element from the main transition-metal groups (groups 511). This is also the first example of a structurally characterized mer-triaqua complex with terpyridine for any transition metal. Acid dissociation constants, pK a1 and pK a2, of the triaqua complex are determined to be 3.0 and 6.9, respectively.

元の言語英語
ページ(範囲)116-118
ページ数3
ジャーナルChemistry Letters
41
発行部数1
DOI
出版物ステータス出版済み - 1 6 2012

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Transition metals
Ligands
Chemical elements
Acids

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

A mer-Triaqua Rh complex with a terpyridine ligand. / Inoki, Daisuke; Matsumoto, Takahiro; Nakai, Hidetaka; Ogo, Seiji.

:: Chemistry Letters, 巻 41, 番号 1, 06.01.2012, p. 116-118.

研究成果: ジャーナルへの寄稿記事

Inoki, Daisuke ; Matsumoto, Takahiro ; Nakai, Hidetaka ; Ogo, Seiji. / A mer-Triaqua Rh complex with a terpyridine ligand. :: Chemistry Letters. 2012 ; 巻 41, 番号 1. pp. 116-118.
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