A mer-Triaqua Rh complex with a terpyridine ligand

Daisuke Inoki, Takahiro Matsumoto, Hidetaka Nakai, Seiji Ogo

    研究成果: Contribution to journalArticle査読

    1 被引用数 (Scopus)

    抄録

    We report the synthesis of a mer-triaqua Rh III complex using terpyridine as a meridional tridentate ligand. This is the first example of a structurally characterized six-coordinated mertriaqua complex for any second- or third-row element from the main transition-metal groups (groups 511). This is also the first example of a structurally characterized mer-triaqua complex with terpyridine for any transition metal. Acid dissociation constants, pK a1 and pK a2, of the triaqua complex are determined to be 3.0 and 6.9, respectively.

    本文言語英語
    ページ(範囲)116-118
    ページ数3
    ジャーナルChemistry Letters
    41
    1
    DOI
    出版ステータス出版済み - 2012

    All Science Journal Classification (ASJC) codes

    • 化学 (全般)

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