A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

Zhao Yang Li, Jing Wei Dai, Kevin J. Gagnon, Hong Ling Cai, Takashi Yamamoto, Yasuaki Einaga, Han Hua Zhao, Shinji Kanegawa, Osamu Sato, Kim R. Dunbar, Ren Gen Xiong

研究成果: ジャーナルへの寄稿学術誌査読

25 被引用数 (Scopus)

抄録

The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

本文言語英語
ページ(範囲)14685-14688
ページ数4
ジャーナルDalton Transactions
42
41
DOI
出版ステータス出版済み - 11月 7 2013

!!!All Science Journal Classification (ASJC) codes

  • 無機化学

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