A new entry to doubly N-confused [26]hexaphyrins(1.1.1.1.1.1) from normal [26]hexaphyrins(1.1.1.1.1.1) through an unprecedented double pyrrolic rearrangement

Masaaki Suzuki, Min Chul Yoon, Deok Yun Kim, Jung Ho Kwon, Hiroyuki Furuta, Dongho Kim, Atsuhiro Osuka

    研究成果: Contribution to journalArticle査読

    55 被引用数 (Scopus)

    抄録

    Treatment of hexakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1) (1) with CuCl in the presence of pyridine and molecular oxygen led to formation of doubly N-confused [26]hexaphyrin(1.1.1.1.1.1) 2 in a moderate yield through an unprecedented double pyrrolic rearrangement. Macrocycle 2 has been shown to serve as an effective bis-metal-coordinating ligand and exhibits attractive optical properties such as a sharp Soret-like band at 566 nm and low-energy fluorescence at 1058 nm.

    本文言語英語
    ページ(範囲)1754-1759
    ページ数6
    ジャーナルChemistry - A European Journal
    12
    6
    DOI
    出版ステータス出版済み - 2 8 2006

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

    フィンガープリント 「A new entry to doubly N-confused [26]hexaphyrins(1.1.1.1.1.1) from normal [26]hexaphyrins(1.1.1.1.1.1) through an unprecedented double pyrrolic rearrangement」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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