A new mononuclear iron(III) complex containing a peroxocarbonate ligand

Koji Hashimoto, Shigenori Nagatomo, Shuhei Fujinami, Hideki Furutachi, Seiji Ogo, Masatatsu Suzuki, Akira Uehara, Yonezo Maeda, Yoshihito Watanabe, Teizo Kitagawa

研究成果: ジャーナルへの寄稿記事

49 引用 (Scopus)

抄録

Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.

元の言語英語
ページ(範囲)1202-1205
ページ数4
ジャーナルAngewandte Chemie - International Edition
41
発行部数7
DOI
出版物ステータス出版済み - 4 2 2002

Fingerprint

Iron
Ligands
Coordination Complexes
Peroxides
Metal complexes
Transition metals
Anions
Negative ions
Stabilization
Acids
quinaldic acid

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

これを引用

A new mononuclear iron(III) complex containing a peroxocarbonate ligand. / Hashimoto, Koji; Nagatomo, Shigenori; Fujinami, Shuhei; Furutachi, Hideki; Ogo, Seiji; Suzuki, Masatatsu; Uehara, Akira; Maeda, Yonezo; Watanabe, Yoshihito; Kitagawa, Teizo.

:: Angewandte Chemie - International Edition, 巻 41, 番号 7, 02.04.2002, p. 1202-1205.

研究成果: ジャーナルへの寄稿記事

Hashimoto, K, Nagatomo, S, Fujinami, S, Furutachi, H, Ogo, S, Suzuki, M, Uehara, A, Maeda, Y, Watanabe, Y & Kitagawa, T 2002, 'A new mononuclear iron(III) complex containing a peroxocarbonate ligand', Angewandte Chemie - International Edition, 巻. 41, 番号 7, pp. 1202-1205. https://doi.org/10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E
Hashimoto, Koji ; Nagatomo, Shigenori ; Fujinami, Shuhei ; Furutachi, Hideki ; Ogo, Seiji ; Suzuki, Masatatsu ; Uehara, Akira ; Maeda, Yonezo ; Watanabe, Yoshihito ; Kitagawa, Teizo. / A new mononuclear iron(III) complex containing a peroxocarbonate ligand. :: Angewandte Chemie - International Edition. 2002 ; 巻 41, 番号 7. pp. 1202-1205.
@article{798e6d9defec4e5f96a60818bf7e393b,
title = "A new mononuclear iron(III) complex containing a peroxocarbonate ligand",
abstract = "Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.",
author = "Koji Hashimoto and Shigenori Nagatomo and Shuhei Fujinami and Hideki Furutachi and Seiji Ogo and Masatatsu Suzuki and Akira Uehara and Yonezo Maeda and Yoshihito Watanabe and Teizo Kitagawa",
year = "2002",
month = "4",
day = "2",
doi = "10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E",
language = "English",
volume = "41",
pages = "1202--1205",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "7",

}

TY - JOUR

T1 - A new mononuclear iron(III) complex containing a peroxocarbonate ligand

AU - Hashimoto, Koji

AU - Nagatomo, Shigenori

AU - Fujinami, Shuhei

AU - Furutachi, Hideki

AU - Ogo, Seiji

AU - Suzuki, Masatatsu

AU - Uehara, Akira

AU - Maeda, Yonezo

AU - Watanabe, Yoshihito

AU - Kitagawa, Teizo

PY - 2002/4/2

Y1 - 2002/4/2

N2 - Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.

AB - Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.

UR - http://www.scopus.com/inward/record.url?scp=0037006848&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037006848&partnerID=8YFLogxK

U2 - 10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E

DO - 10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E

M3 - Article

C2 - 12491259

AN - SCOPUS:0037006848

VL - 41

SP - 1202

EP - 1205

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 7

ER -