抄録
Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.
元の言語 | 英語 |
---|---|
ページ(範囲) | 1202-1205 |
ページ数 | 4 |
ジャーナル | Angewandte Chemie - International Edition |
巻 | 41 |
発行部数 | 7 |
DOI | |
出版物ステータス | 出版済み - 4 2 2002 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
これを引用
A new mononuclear iron(III) complex containing a peroxocarbonate ligand. / Hashimoto, Koji; Nagatomo, Shigenori; Fujinami, Shuhei; Furutachi, Hideki; Ogo, Seiji; Suzuki, Masatatsu; Uehara, Akira; Maeda, Yonezo; Watanabe, Yoshihito; Kitagawa, Teizo.
:: Angewandte Chemie - International Edition, 巻 41, 番号 7, 02.04.2002, p. 1202-1205.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - A new mononuclear iron(III) complex containing a peroxocarbonate ligand
AU - Hashimoto, Koji
AU - Nagatomo, Shigenori
AU - Fujinami, Shuhei
AU - Furutachi, Hideki
AU - Ogo, Seiji
AU - Suzuki, Masatatsu
AU - Uehara, Akira
AU - Maeda, Yonezo
AU - Watanabe, Yoshihito
AU - Kitagawa, Teizo
PY - 2002/4/2
Y1 - 2002/4/2
N2 - Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.
AB - Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.
UR - http://www.scopus.com/inward/record.url?scp=0037006848&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037006848&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E
DO - 10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E
M3 - Article
C2 - 12491259
AN - SCOPUS:0037006848
VL - 41
SP - 1202
EP - 1205
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 7
ER -