A New Synthetic Method for Natural Products Using Butadiene Telomers Obtained by Palladium-catalyzed Telomerization

Jiro Tsuji, Takashi Takahashi, Isao Shimizu, Hideo Nagashima

研究成果: Contribution to journalArticle査読

3 被引用数 (Scopus)

抄録

Butadiene telomers, easily prepared by the palladium-catalyzed telomerization of butadiene with various nucleophiles are extremely useful starting materials for natural product syntheses. The following natural products were synthesized in short steps by using several butadiene telomers : Steroid (19-nortestosterone), macrolides (diplodialides, 9-decanolides, lasiodiplodin, zearalenone, recifeiolide, curvularin), Matsutake alcohol, lipoic acid, pellitorin, dihydrojasmone, methyl dihydrojasmonate, muscone, civetone, pyrethrolone, 12-acetoxy-l,3-dodecadiene, royal jelly acids and queen substance. In these syntheses, Wacker type oxidation of terminal double bonds to methyl ketones catalyzed by PdCl2-CuCl is used in key steps.

本文言語英語
ページ(範囲)219-233
ページ数15
ジャーナルJournal of Synthetic Organic Chemistry, Japan
38
3
DOI
出版ステータス出版済み - 1980

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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