A novel isoindole-containing polyaromatic hydrocarbon unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin

Yuta Shiina; Hideaki Karasaki; Shigeki Mori; Nagao Kobayashi; Hiroyuki Furuta; Soji Shimizu

doi:10.1142/S1088424616500541

A novel isoindole-containing polyaromatic hydrocarbon unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin

Yuta Shiina, Hideaki Karasaki, Shigeki Mori, Nagao Kobayashi, Hiroyuki Furuta, Soji Shimizu

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

4 被引用数 (Scopus)

抄録

A novel isoindole-containing polyaromatic hydrocarbon was unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin from a reaction of phthalimide and 2,6-dichlorophenylacetic acid in the presence of boric acid. Due to the highly annulated structure, this molecule exhibited blue color in solution, which was theoretically well reproduced by the HOMO-LUMO transitions based on the time-dependent DFT calculation. In this manuscript, the synthesis and properties of this polyaromatic hydrocarbon and meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin are reported.

本文言語	英語
ページ（範囲）	1049-1054
ページ数	6
ジャーナル	Journal of Porphyrins and Phthalocyanines
巻	20
号	8-11
DOI	https://doi.org/10.1142/S1088424616500541
出版ステータス	出版済み - 8月 1 2016

!!!All Science Journal Classification (ASJC) codes

化学 (全般)

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10.1142/S1088424616500541

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引用スタイル

A novel isoindole-containing polyaromatic hydrocarbon unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin. / Shiina, Yuta; Karasaki, Hideaki; Mori, Shigeki その他.

In: Journal of Porphyrins and Phthalocyanines, Vol. 20, No. 8-11, 01.08.2016, p. 1049-1054.

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

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abstract = "A novel isoindole-containing polyaromatic hydrocarbon was unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin from a reaction of phthalimide and 2,6-dichlorophenylacetic acid in the presence of boric acid. Due to the highly annulated structure, this molecule exhibited blue color in solution, which was theoretically well reproduced by the HOMO-LUMO transitions based on the time-dependent DFT calculation. In this manuscript, the synthesis and properties of this polyaromatic hydrocarbon and meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin are reported.",

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