TY - JOUR
T1 - A novel isoindole-containing polyaromatic hydrocarbon unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin
AU - Shiina, Yuta
AU - Karasaki, Hideaki
AU - Mori, Shigeki
AU - Kobayashi, Nagao
AU - Furuta, Hiroyuki
AU - Shimizu, Soji
N1 - Publisher Copyright:
© 2016 World Scientific Publishing Company.
PY - 2016/8/1
Y1 - 2016/8/1
N2 - A novel isoindole-containing polyaromatic hydrocarbon was unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin from a reaction of phthalimide and 2,6-dichlorophenylacetic acid in the presence of boric acid. Due to the highly annulated structure, this molecule exhibited blue color in solution, which was theoretically well reproduced by the HOMO-LUMO transitions based on the time-dependent DFT calculation. In this manuscript, the synthesis and properties of this polyaromatic hydrocarbon and meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin are reported.
AB - A novel isoindole-containing polyaromatic hydrocarbon was unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin from a reaction of phthalimide and 2,6-dichlorophenylacetic acid in the presence of boric acid. Due to the highly annulated structure, this molecule exhibited blue color in solution, which was theoretically well reproduced by the HOMO-LUMO transitions based on the time-dependent DFT calculation. In this manuscript, the synthesis and properties of this polyaromatic hydrocarbon and meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin are reported.
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U2 - 10.1142/S1088424616500541
DO - 10.1142/S1088424616500541
M3 - Article
AN - SCOPUS:84980336421
VL - 20
SP - 1049
EP - 1054
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
SN - 1088-4246
IS - 8-11
ER -