A novel isoindole-containing polyaromatic hydrocarbon unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin

Yuta Shiina, Hideaki Karasaki, Shigeki Mori, Nagao Kobayashi, Hiroyuki Furuta, Soji Shimizu

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

A novel isoindole-containing polyaromatic hydrocarbon was unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin from a reaction of phthalimide and 2,6-dichlorophenylacetic acid in the presence of boric acid. Due to the highly annulated structure, this molecule exhibited blue color in solution, which was theoretically well reproduced by the HOMO-LUMO transitions based on the time-dependent DFT calculation. In this manuscript, the synthesis and properties of this polyaromatic hydrocarbon and meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin are reported.

元の言語英語
ページ(範囲)1049-1054
ページ数6
ジャーナルJournal of Porphyrins and Phthalocyanines
20
発行部数8-11
DOI
出版物ステータス出版済み - 8 1 2016

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Isoindoles
Hydrocarbons
Discrete Fourier transforms
Color
Molecules
Acids

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

A novel isoindole-containing polyaromatic hydrocarbon unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin. / Shiina, Yuta; Karasaki, Hideaki; Mori, Shigeki; Kobayashi, Nagao; Furuta, Hiroyuki; Shimizu, Soji.

:: Journal of Porphyrins and Phthalocyanines, 巻 20, 番号 8-11, 01.08.2016, p. 1049-1054.

研究成果: ジャーナルへの寄稿記事

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abstract = "A novel isoindole-containing polyaromatic hydrocarbon was unexpectedly formed during the synthesis of meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin from a reaction of phthalimide and 2,6-dichlorophenylacetic acid in the presence of boric acid. Due to the highly annulated structure, this molecule exhibited blue color in solution, which was theoretically well reproduced by the HOMO-LUMO transitions based on the time-dependent DFT calculation. In this manuscript, the synthesis and properties of this polyaromatic hydrocarbon and meso-2,6-dichlorophenyl-substituted tribenzosubporphyrin are reported.",
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AU - Shimizu, Soji

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