A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: Spontaneous resolution and photoresponsive properties

Wen Zhang; Hao Ling Sun; Osamu Sato

doi:10.1039/c0ce00178c

A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: Spontaneous resolution and photoresponsive properties

Wen Zhang, Hao Ling Sun, Osamu Sato

物質基盤化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

27 被引用数 (Scopus)

抄録

A one-dimensional homochiral Mo^IVCu^II compound, [Cu(tren)][Cu(33)][Mo(CN)₈]·4H₂O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P2₁. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.

本文言語	英語
ページ（範囲）	4045-4047
ページ数	3
ジャーナル	CrystEngComm
巻	12
号	12
DOI	https://doi.org/10.1039/c0ce00178c
出版ステータス	出版済み - 12月 1 2010

!!!All Science Journal Classification (ASJC) codes

化学 (全般)
材料科学（全般）
凝縮系物理学

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10.1039/c0ce00178c

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title = "A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: Spontaneous resolution and photoresponsive properties",

abstract = "A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.",

author = "Wen Zhang and Sun, {Hao Ling} and Osamu Sato",

year = "2010",

month = dec,

day = "1",

doi = "10.1039/c0ce00178c",

language = "English",

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T1 - A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer

T2 - Spontaneous resolution and photoresponsive properties

AU - Zhang, Wen

AU - Sun, Hao Ling

AU - Sato, Osamu

PY - 2010/12/1

Y1 - 2010/12/1

N2 - A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.

AB - A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.

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JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 12

ER -

A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: Spontaneous resolution and photoresponsive properties

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!!!All Science Journal Classification (ASJC) codes

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