A Polyaromatic Molecular Clip That Enables the Binding of Planar, Tubular, and Dendritic Compounds

Keisuke Jono, Akira Suzuki, Munetaka Akita, Ken Albrecht, Kimihisa Yamamoto, Michito Yoshizawa

研究成果: Contribution to journalArticle査読

15 被引用数 (Scopus)

抄録

By the covalent linkage of two bent bisanthracene amphiphiles with a biphenyl spacer bearing hydrophilic pendants, we synthesized a new molecular clip with a C-shaped conformation. The molecular clip provides an acyclic, open cavity surrounded by four anthracene panels in water. In contrast to previous clip- and tweezers-like compounds as well as cage-shaped compounds, the C-shaped polyaromatic cavity displays unusual wide-ranging capturing abilities toward not only planar perylene-based pigments and cylindrical single-walled carbon nanotubes but also highly branched macromolecules (carbazole dendrimers).

本文言語英語
ページ(範囲)3570-3574
ページ数5
ジャーナルAngewandte Chemie - International Edition
56
13
DOI
出版ステータス出版済み - 3 20 2017
外部発表はい

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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