A series of trinuclear CuIILnIIICuII complexes derived from 2,6-di(acetoacetyl)pyridine: Synthesis, structure, and magnetism

Takuya Shiga, Masaaki Ohba, Hisashi Õkawa

研究成果: Contribution to journalArticle査読

78 被引用数 (Scopus)

抄録

A series of trinuclear CuIILnIIICuII complexes with the bridging ligand 2,6-di(acetoacetyl)pyridine have been prepared by one-pot reaction with Cu(NO3)2·3H 2O and Ln(NO3)3·nH2O in methanol. X-ray crystallographic studies for all the complexes indicate that two L2- ligands selectively sandwich two Cu(II) ions with the 1,3-diketonate entities and one Ln(III) ion with the 2,6-acetylpyridine entity to form a trinuclear CuLnCu core bridged by the enolate oxygen atoms. Cryomagnetic properties of the complexes are studied with respect to the electronic structure of the Ln ion.

本文言語英語
ページ(範囲)4435-4446
ページ数12
ジャーナルInorganic chemistry
43
14
DOI
出版ステータス出版済み - 7 12 2004

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

フィンガープリント 「A series of trinuclear Cu<sup>II</sup>Ln<sup>III</sup>Cu<sup>II</sup> complexes derived from 2,6-di(acetoacetyl)pyridine: Synthesis, structure, and magnetism」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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