A Stable Non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Taro Koide, Ko Furukawa, Hiroshi Shinokubo, Jae Yoon Shin, Kil Suk Kim, Dongho Kim, Atsuhiro Osuka

研究成果: ジャーナルへの寄稿記事

63 引用 (Scopus)

抄録

A meso, meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekulé singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C-O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.

元の言語英語
ページ(範囲)7246-7247
ページ数2
ジャーナルJournal of the American Chemical Society
132
発行部数21
DOI
出版物ステータス出版済み - 6 2 2010
外部発表Yes

Fingerprint

Porphyrins
Electronic states
Electrons

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

これを引用

A Stable Non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1). / Koide, Taro; Furukawa, Ko; Shinokubo, Hiroshi; Shin, Jae Yoon; Kim, Kil Suk; Kim, Dongho; Osuka, Atsuhiro.

:: Journal of the American Chemical Society, 巻 132, 番号 21, 02.06.2010, p. 7246-7247.

研究成果: ジャーナルへの寄稿記事

Koide, Taro ; Furukawa, Ko ; Shinokubo, Hiroshi ; Shin, Jae Yoon ; Kim, Kil Suk ; Kim, Dongho ; Osuka, Atsuhiro. / A Stable Non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1). :: Journal of the American Chemical Society. 2010 ; 巻 132, 番号 21. pp. 7246-7247.
@article{1b3da4e2a07840c2a59c3aea237c2a4d,
title = "A Stable Non-Kekul{\'e} singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)",
abstract = "A meso, meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekul{\'e} singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C-O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.",
author = "Taro Koide and Ko Furukawa and Hiroshi Shinokubo and Shin, {Jae Yoon} and Kim, {Kil Suk} and Dongho Kim and Atsuhiro Osuka",
year = "2010",
month = "6",
day = "2",
doi = "10.1021/ja101040s",
language = "English",
volume = "132",
pages = "7246--7247",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "21",

}

TY - JOUR

T1 - A Stable Non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

AU - Koide, Taro

AU - Furukawa, Ko

AU - Shinokubo, Hiroshi

AU - Shin, Jae Yoon

AU - Kim, Kil Suk

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2010/6/2

Y1 - 2010/6/2

N2 - A meso, meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekulé singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C-O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.

AB - A meso, meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekulé singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C-O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.

UR - http://www.scopus.com/inward/record.url?scp=77952852461&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77952852461&partnerID=8YFLogxK

U2 - 10.1021/ja101040s

DO - 10.1021/ja101040s

M3 - Article

C2 - 20455537

AN - SCOPUS:77952852461

VL - 132

SP - 7246

EP - 7247

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 21

ER -