TY - JOUR
T1 - A stable single piece of unimolecularly π-stacked porphyrin aggregate in a thixotropic low molecular weight gel
T2 - A one-dimensional molecular template for polydiacetylene wiring up to several tens of micrometers in length
AU - Shirakawa, Michihiro
AU - Fujita, Norifumi
AU - Shinkai, Seiji
PY - 2005/3/30
Y1 - 2005/3/30
N2 - An amide-type copper porphyrin gelator having alkyldiacetylene tethers gives very transparent gel in Decalin, and the gel shows unique thixotropic behavior. One-dimensional aggregates generated in the gel act as templates for unimolecularly segregated polydiacetylene wiring upon UV irradiation on the surface. The polymerization along the aggregation goes to at least several micrometers long.
AB - An amide-type copper porphyrin gelator having alkyldiacetylene tethers gives very transparent gel in Decalin, and the gel shows unique thixotropic behavior. One-dimensional aggregates generated in the gel act as templates for unimolecularly segregated polydiacetylene wiring upon UV irradiation on the surface. The polymerization along the aggregation goes to at least several micrometers long.
UR - http://www.scopus.com/inward/record.url?scp=16244391781&partnerID=8YFLogxK
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U2 - 10.1021/ja042869d
DO - 10.1021/ja042869d
M3 - Article
C2 - 15783186
AN - SCOPUS:16244391781
SN - 0002-7863
VL - 127
SP - 4164
EP - 4165
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 12
ER -