抜粋
The reaction of 1, 1-diphenylethylene with sulfuric acid was studied at 30ŶC in dichloroethane by stopped-flow/rapid-scan spectroscopy coupled with the rapid-quenching technique. Rapid-scan spectra showed the formation and decay of two species absorbing at 435 and 465 nm during a period of less than one second. These species were detected only when sulfuric acid was 100% or more. The 435-nm species was the monomeric cation formed by protonation, and the 465-nm species was conceivably a charge-transfer complex of diphenylethylene and SO3. The latter species eventually gave cyclic sulfones.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 245-250 |
| ページ数 | 6 |
| ジャーナル | Polymer Journal |
| 巻 | 12 |
| 発行部数 | 4 |
| DOI | |
| 出版物ステータス | 出版済み - 4 1980 |
All Science Journal Classification (ASJC) codes
- Polymers and Plastics
- Materials Chemistry
フィンガープリント A stopped-flow/rapid-quenching study of the reaction of 1, 1-diphenylethylene sulfuric acid' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。
これを引用
Kunihide, T., & Toyoki, K. (1980). A stopped-flow/rapid-quenching study of the reaction of 1, 1-diphenylethylene sulfuric acid. Polymer Journal, 12(4), 245-250. https://doi.org/10.1295/polymj.12.245