A tetranuclear-zinc-cluster-catalyzed practical and versatile deprotection of acetates and benzoates

Takanori Iwasaki, Kazushi Agura, Yusuke Maegawa, Yukiko Hayashi, Takashi Ohshima, Kazushi Mashima

研究成果: Contribution to journalArticle査読

35 被引用数 (Scopus)

抄録

A new catalytic deacylation of acetates and benzoates through transesterification with methanol was developed (see scheme). Reactions with various acidand nucleophile-sensitive functional groups proceeded efficiently in the presence of a catalytic amount of the tetranuclear zinc cluster. The present catalysis is applicable to less-reactive tertiary acetates, the deacylation of which is difficult to achieve by transesterification with other catalysts.

本文言語英語
ページ(範囲)11567-11571
ページ数5
ジャーナルChemistry - A European Journal
16
38
DOI
出版ステータス出版済み - 10 11 2010

All Science Journal Classification (ASJC) codes

  • 触媒
  • 有機化学

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