A theoretical basis for the enhancement of Seebeck coefficients in supramolecular thermocells

Yimin Liang, Hongyao Zhou, Teppei Yamada, Nobuo Kimizuka

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

Seebeck coefficients (Se) of supramolecular thermocells harnessing four kinds of cyclodextrins as host molecules were investigated. Theoretical analysis revealed that association enthalpy between the hosts and triiodide has a major influence on the Seebeck coefficients of the thermocells. Thermodynamic parameters of hostguest associations were evaluated by isothermal titration calorimetry, which is in good agreement with the theoretically estimated values from thermocell measurements. This result provides a guideline to estimate Seebeck coefficient of supramolecular thermocells and to determine the thermodynamic parameters.

本文言語英語
ページ(範囲)1142-1147
ページ数6
ジャーナルBulletin of the Chemical Society of Japan
92
7
DOI
出版ステータス出版済み - 2019

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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