A theoretical study of spin-orbit coupling in an Fe(II) spin-crossover complex. Mechanism of the LIESST effect

Masakazu Kondo, Kazunari Yoshizawa

研究成果: ジャーナルへの寄稿記事

17 引用 (Scopus)

抄録

Spin-orbit coupling (SOC) in an Fe(II) spin-crossover system, [Fe(2-pic)3]Cl2·EtOH, where 2-pic denotes 2-picolylamine, is studied to understand the mechanism of light-induced excited spin state trapping (LIESST). The effects of SOC between the 1T1(1T2, 5E) states and the 3T2 state are larger than those between the 1T1(1T2, 5E) states and the 3T1 state. This suggests that the 3T2 state can play a significant role in the LIESST and reverse-LIESST effects.

元の言語英語
ページ(範囲)519-523
ページ数5
ジャーナルChemical Physics Letters
372
発行部数3-4
DOI
出版物ステータス出版済み - 4 29 2003

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crossovers
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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

これを引用

A theoretical study of spin-orbit coupling in an Fe(II) spin-crossover complex. Mechanism of the LIESST effect. / Kondo, Masakazu; Yoshizawa, Kazunari.

:: Chemical Physics Letters, 巻 372, 番号 3-4, 29.04.2003, p. 519-523.

研究成果: ジャーナルへの寄稿記事

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