Absolute configuration of 2-hydroxy-2-(1-naphthyl)propionic acid as determined by the 1H NMR anisotropy method

Akio Ichikawa, Shuntaro Hiradate, Akinori Sugio, Shunsuke Kuwahara, Masataka Watanabe, Nobuyuki Harada

研究成果: Contribution to journalArticle査読

44 被引用数 (Scopus)

抄録

Enantiopure 2-hydroxy-2-(1-naphthyl)propionic acid (+)-2 was prepared by the stereoselective Grignard reaction of 1-naphthylmagnesium bromide with (1R,3R,4S)-menthyl pyruvate 3 or (1R,3R,4S)-8-phenylmenthyl pyruvate 4, and the absolute configuration of acid (+)-2 was unambiguously determined to be S by the 1H NMR anisotropy method.

本文言語英語
ページ(範囲)4075-4078
ページ数4
ジャーナルTetrahedron Asymmetry
10
21
DOI
出版ステータス出版済み - 10 29 1999
外部発表はい

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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