Acid-base equilibrium constants at the water surface and distribution coefficients between the surface and the bulk as studied by the laser two-photon ionization technique

Miki Sato, Takeshi Kaieda, Kohshin Ohmukai, Hirofumi Kawazumi, Akira Harata, Teiichiro Ogawa

    研究成果: ジャーナルへの寄稿記事

    8 引用 (Scopus)

    抄録

    A new method has been proposed to determine the equilibrium between the bulk and the surface by directly measuring surface concentrations using laser two-photon ionization. This method has been applied to pyrenebutyric acid. The surface concentrations depended on the pH of the solution and were analyzed on the basis of two equilibrium constants and two distribution coefficients. Most pyrenebutyric acid stays on the surface at pH = 2.2. The equilibrium constant, pKa, of pyrenebutyric acid on the water surface was determined to be 7.85 ± 0.13, and this value is shifted to higher value than that in the bulk (4.76). The distribution coefficient of the neutral pyrenebutyric acid was determined as (5.9 ± 2.8) × 10-2 m, and that of pyrenebutyric anion as (4.82 ± 0.1) × 10-5 m. The ratio of the distribution coefficient of the neutral pyrenebutyric acid to that of pyrenebutyric anion was determined to be (1.2 ± 0.6) × 103. These findings indicate that the equilibrium shifts toward the neutral form on the water surface. Laser two-photon ionization was found to be a sensitive and powerful technique to analyze equilibrium on the surface and that between the surface and the bulk.

    元の言語英語
    ページ(範囲)9873-9877
    ページ数5
    ジャーナルJournal of Physical Chemistry B
    104
    発行部数42
    出版物ステータス出版済み - 10 26 2000

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    acid base equilibrium
    Equilibrium constants
    surface water
    Ionization
    Photons
    ionization
    Water
    Lasers
    photons
    coefficients
    acids
    lasers
    Acids
    anions
    Anions
    Negative ions
    guy wires
    Acid-Base Equilibrium
    shift
    1-pyrenebutyrate

    All Science Journal Classification (ASJC) codes

    • Physical and Theoretical Chemistry
    • Surfaces, Coatings and Films
    • Materials Chemistry

    これを引用

    Acid-base equilibrium constants at the water surface and distribution coefficients between the surface and the bulk as studied by the laser two-photon ionization technique. / Sato, Miki; Kaieda, Takeshi; Ohmukai, Kohshin; Kawazumi, Hirofumi; Harata, Akira; Ogawa, Teiichiro.

    :: Journal of Physical Chemistry B, 巻 104, 番号 42, 26.10.2000, p. 9873-9877.

    研究成果: ジャーナルへの寄稿記事

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    abstract = "A new method has been proposed to determine the equilibrium between the bulk and the surface by directly measuring surface concentrations using laser two-photon ionization. This method has been applied to pyrenebutyric acid. The surface concentrations depended on the pH of the solution and were analyzed on the basis of two equilibrium constants and two distribution coefficients. Most pyrenebutyric acid stays on the surface at pH = 2.2. The equilibrium constant, pKa, of pyrenebutyric acid on the water surface was determined to be 7.85 ± 0.13, and this value is shifted to higher value than that in the bulk (4.76). The distribution coefficient of the neutral pyrenebutyric acid was determined as (5.9 ± 2.8) × 10-2 m, and that of pyrenebutyric anion as (4.82 ± 0.1) × 10-5 m. The ratio of the distribution coefficient of the neutral pyrenebutyric acid to that of pyrenebutyric anion was determined to be (1.2 ± 0.6) × 103. These findings indicate that the equilibrium shifts toward the neutral form on the water surface. Laser two-photon ionization was found to be a sensitive and powerful technique to analyze equilibrium on the surface and that between the surface and the bulk.",
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    AU - Sato, Miki

    AU - Kaieda, Takeshi

    AU - Ohmukai, Kohshin

    AU - Kawazumi, Hirofumi

    AU - Harata, Akira

    AU - Ogawa, Teiichiro

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    AB - A new method has been proposed to determine the equilibrium between the bulk and the surface by directly measuring surface concentrations using laser two-photon ionization. This method has been applied to pyrenebutyric acid. The surface concentrations depended on the pH of the solution and were analyzed on the basis of two equilibrium constants and two distribution coefficients. Most pyrenebutyric acid stays on the surface at pH = 2.2. The equilibrium constant, pKa, of pyrenebutyric acid on the water surface was determined to be 7.85 ± 0.13, and this value is shifted to higher value than that in the bulk (4.76). The distribution coefficient of the neutral pyrenebutyric acid was determined as (5.9 ± 2.8) × 10-2 m, and that of pyrenebutyric anion as (4.82 ± 0.1) × 10-5 m. The ratio of the distribution coefficient of the neutral pyrenebutyric acid to that of pyrenebutyric anion was determined to be (1.2 ± 0.6) × 103. These findings indicate that the equilibrium shifts toward the neutral form on the water surface. Laser two-photon ionization was found to be a sensitive and powerful technique to analyze equilibrium on the surface and that between the surface and the bulk.

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