Aerobic oxidative homocoupling of aryl amines using heterogeneous rhodium catalysts

Kenji Matsumoto, Kento Dougomori, Shohei Tachikawa, Takanori Ishii, Mitsuru Shindo

研究成果: Contribution to journalArticle査読

34 被引用数 (Scopus)

抄録

The first heterogeneous catalyzed oxidative coupling of aryl amines is reported. Aryl amines were dimerized at room temperature under air using a heterogeneous Rh/C catalyst in the presence of acids. By choosing a suitable acidic solvent, biaryl compounds and carbazoles were selectively prepared in good yields. This reaction is operationally simple and provides an effi cient synthetic methodology for the preparation of biaryl diamines via oxidative C - H activation.

本文言語英語
ページ(範囲)4754-4757
ページ数4
ジャーナルOrganic letters
16
18
DOI
出版ステータス出版済み - 9 19 2014

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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