Aerobic oxidative homocoupling of aryl amines using heterogeneous rhodium catalysts

Kenji Matsumoto; Kento Dougomori; Shohei Tachikawa; Takanori Ishii; Mitsuru Shindo

doi:10.1021/ol502197p

Aerobic oxidative homocoupling of aryl amines using heterogeneous rhodium catalysts

Kenji Matsumoto, Kento Dougomori, Shohei Tachikawa, Takanori Ishii, Mitsuru Shindo

物質基盤化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

38 被引用数 (Scopus)

抄録

The first heterogeneous catalyzed oxidative coupling of aryl amines is reported. Aryl amines were dimerized at room temperature under air using a heterogeneous Rh/C catalyst in the presence of acids. By choosing a suitable acidic solvent, biaryl compounds and carbazoles were selectively prepared in good yields. This reaction is operationally simple and provides an effi cient synthetic methodology for the preparation of biaryl diamines via oxidative C - H activation.

本文言語	英語
ページ（範囲）	4754-4757
ページ数	4
ジャーナル	Organic letters
巻	16
号	18
DOI	https://doi.org/10.1021/ol502197p
出版ステータス	出版済み - 9月 19 2014

!!!All Science Journal Classification (ASJC) codes

生化学
物理化学および理論化学
有機化学

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10.1021/ol502197p

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title = "Aerobic oxidative homocoupling of aryl amines using heterogeneous rhodium catalysts",

abstract = "The first heterogeneous catalyzed oxidative coupling of aryl amines is reported. Aryl amines were dimerized at room temperature under air using a heterogeneous Rh/C catalyst in the presence of acids. By choosing a suitable acidic solvent, biaryl compounds and carbazoles were selectively prepared in good yields. This reaction is operationally simple and provides an effi cient synthetic methodology for the preparation of biaryl diamines via oxidative C - H activation.",

author = "Kenji Matsumoto and Kento Dougomori and Shohei Tachikawa and Takanori Ishii and Mitsuru Shindo",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

year = "2014",

month = sep,

day = "19",

doi = "10.1021/ol502197p",

language = "English",

volume = "16",

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journal = "Organic Letters",

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T1 - Aerobic oxidative homocoupling of aryl amines using heterogeneous rhodium catalysts

AU - Matsumoto, Kenji

AU - Dougomori, Kento

AU - Tachikawa, Shohei

AU - Ishii, Takanori

AU - Shindo, Mitsuru

PY - 2014/9/19

Y1 - 2014/9/19

N2 - The first heterogeneous catalyzed oxidative coupling of aryl amines is reported. Aryl amines were dimerized at room temperature under air using a heterogeneous Rh/C catalyst in the presence of acids. By choosing a suitable acidic solvent, biaryl compounds and carbazoles were selectively prepared in good yields. This reaction is operationally simple and provides an effi cient synthetic methodology for the preparation of biaryl diamines via oxidative C - H activation.

AB - The first heterogeneous catalyzed oxidative coupling of aryl amines is reported. Aryl amines were dimerized at room temperature under air using a heterogeneous Rh/C catalyst in the presence of acids. By choosing a suitable acidic solvent, biaryl compounds and carbazoles were selectively prepared in good yields. This reaction is operationally simple and provides an effi cient synthetic methodology for the preparation of biaryl diamines via oxidative C - H activation.

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U2 - 10.1021/ol502197p

DO - 10.1021/ol502197p

M3 - Article

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JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 18

ER -

Aerobic oxidative homocoupling of aryl amines using heterogeneous rhodium catalysts

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!!!All Science Journal Classification (ASJC) codes

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