Aggregation structure and mechanical properties of polycarbonbate (PC) glycols and polyurethanes incorporating PC glycols

Ken Kojio, Machiko Sakai, Suguru Motokucho, Mutsuhisa Furukawa

研究成果: 著書/レポートタイプへの貢献会議での発言

抄録

Polycarbonate-based polyurethane elastomers (PUEs) were prepared from poly(carbonate) (PC) glycol baring the number of methylene unit of 3-10. Aggregation structure and mechanical properties of these PUEs were investigated by differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and dynamic viscoelatic measurement. The difference in the glass transition temperature of polyols (ΔTg,polyols) and Tg,PUEs (ΔTg) increased with increasing methylene chain length, indicating the degree of microphase separation became weaker with increasing methylene chain length. Magnitude of dynamic storage modulus (E') around rubbery plateau region in the E' curve decreased with increasing methylene chain length due to the change in microphase-separated state and flexibility of the PC glycols.

元の言語英語
ホスト出版物のタイトル55th SPSJ Symposium on Macromolecules
ページ3379-3380
ページ数2
55
エディション2
出版物ステータス出版済み - 2006
外部発表Yes
イベント55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, 日本
継続期間: 9 20 20069 22 2006

その他

その他55th Society of Polymer Science Japan Symposium on Macromolecules
日本
Toyama
期間9/20/069/22/06

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Glycols
Chain length
Elastomers
Polyurethanes
Agglomeration
Mechanical properties
Microphase separation
Polyols
Polycarbonates
Carbonates
Differential scanning calorimetry
Elastic moduli
X ray diffraction

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Kojio, K., Sakai, M., Motokucho, S., & Furukawa, M. (2006). Aggregation structure and mechanical properties of polycarbonbate (PC) glycols and polyurethanes incorporating PC glycols. : 55th SPSJ Symposium on Macromolecules (2 版, 巻 55, pp. 3379-3380)

Aggregation structure and mechanical properties of polycarbonbate (PC) glycols and polyurethanes incorporating PC glycols. / Kojio, Ken; Sakai, Machiko; Motokucho, Suguru; Furukawa, Mutsuhisa.

55th SPSJ Symposium on Macromolecules. 巻 55 2. 編 2006. p. 3379-3380.

研究成果: 著書/レポートタイプへの貢献会議での発言

Kojio, K, Sakai, M, Motokucho, S & Furukawa, M 2006, Aggregation structure and mechanical properties of polycarbonbate (PC) glycols and polyurethanes incorporating PC glycols. : 55th SPSJ Symposium on Macromolecules. 2 Edn, 巻. 55, pp. 3379-3380, 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, 日本, 9/20/06.
Kojio K, Sakai M, Motokucho S, Furukawa M. Aggregation structure and mechanical properties of polycarbonbate (PC) glycols and polyurethanes incorporating PC glycols. : 55th SPSJ Symposium on Macromolecules. 2 版 巻 55. 2006. p. 3379-3380
Kojio, Ken ; Sakai, Machiko ; Motokucho, Suguru ; Furukawa, Mutsuhisa. / Aggregation structure and mechanical properties of polycarbonbate (PC) glycols and polyurethanes incorporating PC glycols. 55th SPSJ Symposium on Macromolecules. 巻 55 2. 版 2006. pp. 3379-3380
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