Alignment dependence of the NH2 chemiluminescence in the reaction of Ar(3P) Atoms with the aligned NH3 molecules

Kazuhiko Ohashi, Toshio Kasai, Dock Chil Che, Keiji Kuwata

研究成果: Contribution to journalArticle査読

10 被引用数 (Scopus)

抄録

An alignment dependence of the NH2(Ã-X̃) chemiluminescence was studied in the reaction of the aligned NH3 molecules and the metastable Ar(3P) atoms by using hexapole state selection. The NH2 emission intensities were analyzed by a hard-sphere model for the NH3 molecule. The ratio of the emission cross sections for the head-on attack and the side-on attack was found to be σhs = 1.2 ± 0.2. The observed alignment dependence is discussed in terms of the interaction between molecular orbitals of NH3 and the atomic orbital of Ar(3P).

本文言語英語
ページ(範囲)5484-5487
ページ数4
ジャーナルJournal of physical chemistry
93
14
DOI
出版ステータス出版済み - 1989
外部発表はい

All Science Journal Classification (ASJC) codes

  • 工学(全般)
  • 物理化学および理論化学

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