抄録
An alignment dependence of the NH2(Ã-X̃) chemiluminescence was studied in the reaction of the aligned NH3 molecules and the metastable Ar(3P) atoms by using hexapole state selection. The NH2 emission intensities were analyzed by a hard-sphere model for the NH3 molecule. The ratio of the emission cross sections for the head-on attack and the side-on attack was found to be σh/σs = 1.2 ± 0.2. The observed alignment dependence is discussed in terms of the interaction between molecular orbitals of NH3 and the atomic orbital of Ar(3P).
本文言語 | 英語 |
---|---|
ページ(範囲) | 5484-5487 |
ページ数 | 4 |
ジャーナル | Journal of physical chemistry |
巻 | 93 |
号 | 14 |
DOI | |
出版ステータス | 出版済み - 1989 |
外部発表 | はい |
!!!All Science Journal Classification (ASJC) codes
- 工学(全般)
- 物理化学および理論化学