Alkaline anion exchange membranes based on KOH-treated multilayer graphene oxide

Thomas Bayer, Benjamin V. Cunning, Roman Selyanchyn, Takeshi Daio, Masamichi Nishihara, Shigenori Fujikawa, Kazunari Sasaki, Stephen M. Lyth

研究成果: ジャーナルへの寄稿記事

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A novel class of alkaline anion exchange membrane (AAEM) is presented, in the form of KOH-modified multilayer graphene oxide paper (GOKOH). Such membranes can be easily fabricated at large scale with varying thickness using conventional filtration techniques, and have high tensile strength (24.5 MPa). However, a large degree of swelling is observed. SEM investigations show that the morphology of GO changes after KOH-treatment, whilst XPS measurements and XRD analysis confirm successful chemical modification. The hydrogen gas permeability is several orders of magnitude lower than conventional polymer-based ionomer membranes. The maximum anion conductivity is 6.1 mS/cm at 70 °C, and the dominant charge carrier is confirmed to be OH- by utilization of anion and proton-conducting blocking layers. The ion exchange capacity is 6.1 mmol/g, measured by titration. A water-mediated reverse Grotthuss-like mechanism is proposed as the main diffusion mode of OH- ions. Finally, a prototype AAEM fuel cell is fabricated using a GOKOH membrane, confirming the applicability to real systems.

元の言語英語
ページ(範囲)51-61
ページ数11
ジャーナルJournal of Membrane Science
508
DOI
出版物ステータス出版済み - 6 15 2016

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All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

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