An Azulene-Fused Tetracene Diimide with a Small HOMO–LUMO Gap

Taro Koide, Moritaka Takesue, Toshihiro Murafuji, Koichiro Satomi, Yasutaka Suzuki, Jun Kawamata, Kengo Terai, Mitsuharu Suzuki, Hiroko Yamada, Yoshihito Shiota, Kazunari Yoshizawa, Fumito Tani

研究成果: Contribution to journalArticle

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A newly prepared tetraazulene-fused tetracene diimide (TA-fused TDI) showed absorption in the near-IR region owing to the effective extension of the π-conjugated system as well as a large two-photon absorption cross-section (σ(2)=2140 GM) at 950 nm. Four reversible reduction processes and n-type semiconductivity were also confirmed as attractive electronic properties of this compound.

元の言語英語
ページ(範囲)1010-1014
ページ数5
ジャーナルChemPlusChem
82
発行部数7
DOI
出版物ステータス出版済み - 8 1 2017

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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    Koide, T., Takesue, M., Murafuji, T., Satomi, K., Suzuki, Y., Kawamata, J., Terai, K., Suzuki, M., Yamada, H., Shiota, Y., Yoshizawa, K., & Tani, F. (2017). An Azulene-Fused Tetracene Diimide with a Small HOMO–LUMO Gap. ChemPlusChem, 82(7), 1010-1014. https://doi.org/10.1002/cplu.201600356