An efficient generation method and remarkable reactivities of 3-triflyloxybenzyne

Suguru Yoshida, Keisuke Uchida, Kazunobu Igawa, Katsuhiko Tomooka, Takamitsu Hosoya

研究成果: ジャーナルへの寄稿記事

47 引用 (Scopus)

抜粋

3-Triflyloxybenzyne was generated via an iodine-magnesium exchange reaction of 1,3-bis(triflyloxy)-2-iodobenzene using the trimethylsilylmethyl Grignard reagent. Various arynophiles and nucleophiles reacted regioselectively with 3-triflyoxybenzyne to afford cycloadducts and unique aryl triflones, which were provided via thia-Fries rearrangement.

元の言語英語
ページ(範囲)15059-15062
ページ数4
ジャーナルChemical Communications
50
発行部数95
DOI
出版物ステータス出版済み - 12 11 2014

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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