An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism

Masaaki Abe, Hiroki Futagawa, Toshikazu Ono, Teppei Yamada, Nobuo Kimizuka, Yoshio Hisaeda

研究成果: Contribution to journalArticle査読

27 被引用数 (Scopus)

抄録

Oxidative electropolymeization of an axially bound, bithiophene-pyridine complex of ruthenium(III)-porphycene [Ru(TPrPc) (btp)2]PF6 (1) gives a submicrometer-thick, polymeric film on an ITO electrode with a crystalline morphology. The polymeric film, the first example of axially linked multimetalloporphycene coordination arrays, exhibits highly stable and reproducible electrochromic response with high electrochromic efficiency upon electrochemical control over the metal-centered electron transfer process (RuII/RuIII).

本文言語英語
ページ(範囲)11061-11063
ページ数3
ジャーナルInorganic chemistry
54
23
DOI
出版ステータス出版済み - 11 16 2015

All Science Journal Classification (ASJC) codes

  • 物理化学および理論化学
  • 無機化学

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「An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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