An Improvement of the Palladium-Catalyzed [4+2] Cycloaddition of o -(Silylmethyl)benzyl Carbonates with Alkenes

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

The palladium complex, which is generated in situ from Pd(η 3-C3H5)Cp and tris(4-methoxy-3,5-dimethylphenyl)phosphine, catalyzed the [4+2] cycloaddition of o-(silylmethyl)benzyl carbonates with alkenes. The reaction of the benzyl esters with methyl crotonate gave methyl 3-methyltetralin-2-carboxylate in 84% yield with 2% catalyst loading.

元の言語英語
記事番号st-2014-u0511-l
ページ(範囲)2488-2492
ページ数5
ジャーナルSynlett
25
発行部数17
DOI
出版物ステータス出版済み - 10 22 2014

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phosphine
Crotonates
Cycloaddition
Carbonates
Palladium
Alkenes
Esters
Catalysts

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

これを引用

An Improvement of the Palladium-Catalyzed [4+2] Cycloaddition of o -(Silylmethyl)benzyl Carbonates with Alkenes. / Jin, Yushu; Ishizuka, Kentaro; Kuwano, Ryoichi.

:: Synlett, 巻 25, 番号 17, st-2014-u0511-l, 22.10.2014, p. 2488-2492.

研究成果: ジャーナルへの寄稿記事

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