An Improvement of the Palladium-Catalyzed [4+2] Cycloaddition of o -(Silylmethyl)benzyl Carbonates with Alkenes

Yushu Jin, Kentaro Ishizuka, Ryoichi Kuwano

研究成果: Contribution to journalArticle査読

1 被引用数 (Scopus)

抄録

The palladium complex, which is generated in situ from Pd(η 3-C3H5)Cp and tris(4-methoxy-3,5-dimethylphenyl)phosphine, catalyzed the [4+2] cycloaddition of o-(silylmethyl)benzyl carbonates with alkenes. The reaction of the benzyl esters with methyl crotonate gave methyl 3-methyltetralin-2-carboxylate in 84% yield with 2% catalyst loading.

本文言語英語
論文番号st-2014-u0511-l
ページ(範囲)2488-2492
ページ数5
ジャーナルSynlett
25
17
DOI
出版ステータス出版済み - 10 22 2014

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

フィンガープリント 「An Improvement of the Palladium-Catalyzed [4+2] Cycloaddition of o -(Silylmethyl)benzyl Carbonates with Alkenes」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル