Anionic copolymerization of 2,3,4,5,6‐pentafluorostyrene and divinylbenzene

Shin Nishimura, Akira Nagai, Akio Takahashi, Tadashi Narita

研究成果: Contribution to journalArticle査読

5 被引用数 (Scopus)

抄録

Anionic copolymerizations of 2,3,4,5,6‐pentafluorostyrene (PFS) with 1,3‐divinylbenzene (m‐DVB) and 1,4‐divinylbenzene (p‐DVB) were performed by using lithium diisopropylamide as an initiator in order to synthesize the fluorine‐containing linear polymer with pendant vinyl groups. The products were soluble copolymers possessing both PFS and DVB monomeric units, and the DVB monomeric unit in copolymer had pendant vinyl group. This copolymerization reaction took a much longer time than that of styrene with DVB. The copolymerization parameter of this system was examined from copolymer composition curves. In this system, m‐DVB was found to be more reactive than p‐DVB. The reactivity of copolymerization was largely influenced by the reactivity of active species. © 1993 John Wiley & Sons, Inc.

本文言語英語
ページ(範囲)135-139
ページ数5
ジャーナルJournal of Polymer Science Part A: Polymer Chemistry
31
1
DOI
出版ステータス出版済み - 1 1 1993
外部発表はい

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

フィンガープリント 「Anionic copolymerization of 2,3,4,5,6‐pentafluorostyrene and divinylbenzene」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル