Annealing effect on adhesion properties of poly(butylene terephthalate)

Takao Izumi, Keiji Tanaka, Ryoichi Narita, Shin Horiuchi, Atsushi Takahara, Tisato Kajiyama

研究成果: ジャーナルへの寄稿記事

2 引用 (Scopus)

抄録

Injection-molded poly(butylene terephthalate) (PBT) is generally annealed at a temperature above the operating temperature to remove residual internal stress and obtain high-dimensional stability. However, this annealing treatment causes poor adhesion property and affected quality and lifetime for the products. In this study, a plausible mechanism for why such problems are caused by the annealing treatment is proposed using additive free PBT. After PBT was annealed under given conditions, surface structure and adhesion strength with an epoxy adhesive were examined. Surface roughness of the PBT film monotonically increased with increasing annealing time, and the tensile adhesive strength concurrently decreased. In addition, the height difference between hill and valley of the surface after adhesive failure became larger, meaning that the failure took place in the PBT phase beneath the interface with the epoxy region. Based on these findings, it was claimed that the poor adhesion of PBT after the annealing treatment originated from a weak boundary layer, which was formed at the outermost surface of PBT. Finally, the presence of the weak boundary layer was directly confirmed by transmission electron microscopy.

元の言語英語
ページ(範囲)325-333
ページ数9
ジャーナルComposite Interfaces
11
発行部数4
DOI
出版物ステータス出版済み - 10 14 2004

Fingerprint

terephthalate
butenes
adhesion
Adhesion
Annealing
adhesives
Adhesives
annealing
residual stress
boundary layers
Residual stresses
Boundary layers
dimensional stability
Dimensional stability
Bond strength (materials)
operating temperature
Surface structure
valleys
surface roughness
Surface roughness

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Physics and Astronomy(all)
  • Surfaces, Coatings and Films

これを引用

Annealing effect on adhesion properties of poly(butylene terephthalate). / Izumi, Takao; Tanaka, Keiji; Narita, Ryoichi; Horiuchi, Shin; Takahara, Atsushi; Kajiyama, Tisato.

:: Composite Interfaces, 巻 11, 番号 4, 14.10.2004, p. 325-333.

研究成果: ジャーナルへの寄稿記事

Izumi, Takao ; Tanaka, Keiji ; Narita, Ryoichi ; Horiuchi, Shin ; Takahara, Atsushi ; Kajiyama, Tisato. / Annealing effect on adhesion properties of poly(butylene terephthalate). :: Composite Interfaces. 2004 ; 巻 11, 番号 4. pp. 325-333.
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AU - Takahara, Atsushi

AU - Kajiyama, Tisato

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N2 - Injection-molded poly(butylene terephthalate) (PBT) is generally annealed at a temperature above the operating temperature to remove residual internal stress and obtain high-dimensional stability. However, this annealing treatment causes poor adhesion property and affected quality and lifetime for the products. In this study, a plausible mechanism for why such problems are caused by the annealing treatment is proposed using additive free PBT. After PBT was annealed under given conditions, surface structure and adhesion strength with an epoxy adhesive were examined. Surface roughness of the PBT film monotonically increased with increasing annealing time, and the tensile adhesive strength concurrently decreased. In addition, the height difference between hill and valley of the surface after adhesive failure became larger, meaning that the failure took place in the PBT phase beneath the interface with the epoxy region. Based on these findings, it was claimed that the poor adhesion of PBT after the annealing treatment originated from a weak boundary layer, which was formed at the outermost surface of PBT. Finally, the presence of the weak boundary layer was directly confirmed by transmission electron microscopy.

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