Anthranoxides as Highly Reactive Arynophiles for the Synthesis of Triptycenes

研究成果: Contribution to journalArticle査読

3 被引用数 (Scopus)

抄録

We report herein an efficient method to synthesize triptycenes by the reaction of benzynes and anthranoxides, which are electron-rich and readily prepared from the corresponding anthrones. Using this method, 1,9-syn-substituted triptycenes were regioselectively obtained employing 3-methoxybenzynes. This method was also applied to synthesize pentiptycenes. A DFT study revealed that the cycloaddition of lithium anthranoxide and benzyne proceeds stepwise.

本文言語英語
ページ(範囲)8506-8510
ページ数5
ジャーナルChemistry - A European Journal
26
39
DOI
出版ステータス出版済み - 7 14 2020

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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