Application of FT-IR for in situ investigation of high temperature electrode reactions

Takuya Murai, Keiji Yashiro, Atsushi Kaimai, Takanori Otake, Hiroshige Matsumoto, Tatsuya Kawada, Junichiro Mizusaki

研究成果: ジャーナルへの寄稿Conference article

10 引用 (Scopus)

抄録

Polarization modulated infrared reflection absorption spectroscopy (PM-IRRAS), which is one of the advanced FT-IR methods, was combined with conventional electrochemical techniques for in situ observation of high temperature electrode reactions at 773 K in oxygen partial pressure of 3 × 104 Pa. PM-IRRAS method can detect surface species selectively with high sensitivity at high temperatures without background measurement to cancel the infrared absorption by gas phase. Two different O2(g), Pt/YSZ electrochemical half cells were prepared as simple models of gas-electrodes. One of them had a working electrode which was composed of uniformly distributed platinum; the other had an island-networked platinum electrode. On the former electrode, PM-IRRAS detected a concentration change of adsorbed oxygen on Pt electrode with controlled cathodic overpotential. On the other hand, for the latter sample that showed smaller cathodic current, the signal of the adsorbed oxygen was suppressed by SiO2 impurity, whose spectrum was detected at 1220 cm- 1 by PM-IRRAS. It was shown that PM-IRRAS gives useful information on the state of adsorbed species which affect the electrode kinetics and the cell performance.

元の言語英語
ページ(範囲)2399-2403
ページ数5
ジャーナルSolid State Ionics
176
発行部数31-34
DOI
出版物ステータス出版済み - 10 1 2005
イベント30th Symposium on Solid State Ionics in Japan -
継続期間: 12 1 200412 3 2004

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infrared reflection
Absorption spectroscopy
Electrodes
electrodes
absorption spectroscopy
Polarization
Infrared radiation
polarization
Temperature
Oxygen
Platinum
platinum
oxygen
Gases
Infrared absorption
yttria-stabilized zirconia
cells
Partial pressure
infrared absorption
partial pressure

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

これを引用

Murai, T., Yashiro, K., Kaimai, A., Otake, T., Matsumoto, H., Kawada, T., & Mizusaki, J. (2005). Application of FT-IR for in situ investigation of high temperature electrode reactions. Solid State Ionics, 176(31-34), 2399-2403. https://doi.org/10.1016/j.ssi.2005.06.029

Application of FT-IR for in situ investigation of high temperature electrode reactions. / Murai, Takuya; Yashiro, Keiji; Kaimai, Atsushi; Otake, Takanori; Matsumoto, Hiroshige; Kawada, Tatsuya; Mizusaki, Junichiro.

:: Solid State Ionics, 巻 176, 番号 31-34, 01.10.2005, p. 2399-2403.

研究成果: ジャーナルへの寄稿Conference article

Murai, T, Yashiro, K, Kaimai, A, Otake, T, Matsumoto, H, Kawada, T & Mizusaki, J 2005, 'Application of FT-IR for in situ investigation of high temperature electrode reactions', Solid State Ionics, 巻. 176, 番号 31-34, pp. 2399-2403. https://doi.org/10.1016/j.ssi.2005.06.029
Murai, Takuya ; Yashiro, Keiji ; Kaimai, Atsushi ; Otake, Takanori ; Matsumoto, Hiroshige ; Kawada, Tatsuya ; Mizusaki, Junichiro. / Application of FT-IR for in situ investigation of high temperature electrode reactions. :: Solid State Ionics. 2005 ; 巻 176, 番号 31-34. pp. 2399-2403.
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AU - Kaimai, Atsushi

AU - Otake, Takanori

AU - Matsumoto, Hiroshige

AU - Kawada, Tatsuya

AU - Mizusaki, Junichiro

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N2 - Polarization modulated infrared reflection absorption spectroscopy (PM-IRRAS), which is one of the advanced FT-IR methods, was combined with conventional electrochemical techniques for in situ observation of high temperature electrode reactions at 773 K in oxygen partial pressure of 3 × 104 Pa. PM-IRRAS method can detect surface species selectively with high sensitivity at high temperatures without background measurement to cancel the infrared absorption by gas phase. Two different O2(g), Pt/YSZ electrochemical half cells were prepared as simple models of gas-electrodes. One of them had a working electrode which was composed of uniformly distributed platinum; the other had an island-networked platinum electrode. On the former electrode, PM-IRRAS detected a concentration change of adsorbed oxygen on Pt electrode with controlled cathodic overpotential. On the other hand, for the latter sample that showed smaller cathodic current, the signal of the adsorbed oxygen was suppressed by SiO2 impurity, whose spectrum was detected at 1220 cm- 1 by PM-IRRAS. It was shown that PM-IRRAS gives useful information on the state of adsorbed species which affect the electrode kinetics and the cell performance.

AB - Polarization modulated infrared reflection absorption spectroscopy (PM-IRRAS), which is one of the advanced FT-IR methods, was combined with conventional electrochemical techniques for in situ observation of high temperature electrode reactions at 773 K in oxygen partial pressure of 3 × 104 Pa. PM-IRRAS method can detect surface species selectively with high sensitivity at high temperatures without background measurement to cancel the infrared absorption by gas phase. Two different O2(g), Pt/YSZ electrochemical half cells were prepared as simple models of gas-electrodes. One of them had a working electrode which was composed of uniformly distributed platinum; the other had an island-networked platinum electrode. On the former electrode, PM-IRRAS detected a concentration change of adsorbed oxygen on Pt electrode with controlled cathodic overpotential. On the other hand, for the latter sample that showed smaller cathodic current, the signal of the adsorbed oxygen was suppressed by SiO2 impurity, whose spectrum was detected at 1220 cm- 1 by PM-IRRAS. It was shown that PM-IRRAS gives useful information on the state of adsorbed species which affect the electrode kinetics and the cell performance.

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