抄録
Radical polymerizations and copolymerizations were carried out in the presence of phenyl tert-butyl nitrone(PBN) and tert-nitrosobutane (t-BuNO), and the structure of the spin adduct formed was investigated by ESR spectroscopy. The polymerization mixture of representative monomers showed ESR patterns that are indicative of the propagating radical being trapped. These trapped radicals were not necessarily very stable and, in most cases, disappeared after long reaction periods. Simultaneous trapping of different propagating radicals was attempted in several copolymerization systems. However, this was generally unsuccessful, because of the large difference in reactivities of the propagating radical with t-BuNO.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 67-81 |
| ページ数 | 15 |
| ジャーナル | J Polym Sci Part A-1 Polym Chem |
| 巻 | 12 |
| 発行部数 | 1 |
| DOI | |
| 出版物ステータス | 出版済み - 1 1 1974 |
| 外部発表 | Yes |
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All Science Journal Classification (ASJC) codes
- Engineering(all)
これを引用
APPLICATION OF SPIN TRAPPING TO RADICAL POLYMERIZATIONS. / Kunitake, Toyoki; Murakami, Shigeru.
：: J Polym Sci Part A-1 Polym Chem, 巻 12, 番号 1, 01.01.1974, p. 67-81.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - APPLICATION OF SPIN TRAPPING TO RADICAL POLYMERIZATIONS.
AU - Kunitake, Toyoki
AU - Murakami, Shigeru
PY - 1974/1/1
Y1 - 1974/1/1
N2 - Radical polymerizations and copolymerizations were carried out in the presence of phenyl tert-butyl nitrone(PBN) and tert-nitrosobutane (t-BuNO), and the structure of the spin adduct formed was investigated by ESR spectroscopy. The polymerization mixture of representative monomers showed ESR patterns that are indicative of the propagating radical being trapped. These trapped radicals were not necessarily very stable and, in most cases, disappeared after long reaction periods. Simultaneous trapping of different propagating radicals was attempted in several copolymerization systems. However, this was generally unsuccessful, because of the large difference in reactivities of the propagating radical with t-BuNO.
AB - Radical polymerizations and copolymerizations were carried out in the presence of phenyl tert-butyl nitrone(PBN) and tert-nitrosobutane (t-BuNO), and the structure of the spin adduct formed was investigated by ESR spectroscopy. The polymerization mixture of representative monomers showed ESR patterns that are indicative of the propagating radical being trapped. These trapped radicals were not necessarily very stable and, in most cases, disappeared after long reaction periods. Simultaneous trapping of different propagating radicals was attempted in several copolymerization systems. However, this was generally unsuccessful, because of the large difference in reactivities of the propagating radical with t-BuNO.
UR - http://www.scopus.com/inward/record.url?scp=0015956952&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0015956952&partnerID=8YFLogxK
U2 - 10.1002/pol.1974.170120107
DO - 10.1002/pol.1974.170120107
M3 - Article
AN - SCOPUS:0015956952
VL - 12
SP - 67
EP - 81
JO - Journal of polymer science. Part A-1, Polymer chemistry
JF - Journal of polymer science. Part A-1, Polymer chemistry
SN - 0449-296X
IS - 1
ER -